(η5-C5Me5)2NbH3

Base Information

Chemical Name:(η5-C5Me5)2NbH3
CAS No.:93558-77-1
Molecular Formula:C₂₀H₃₃Nb
Molecular Weight:366.388
Hs Code.:

Synonyms:(η5-C5Me5)2NbH3

Suppliers and Price of (η5-C5Me5)2NbH3

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Trihydridobis(pentamethylcyclopentadienyl)niobium(V)
500mg
$ 596.00

Strem Chemicals
Trihydridobis(pentamethylcyclopentadienyl)niobium(V)
100mg
$ 150.00

Total 4 raw suppliers

Chemical Property of (η5-C5Me5)2NbH3

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Trihydridobis(pentamethylcyclopentadienyl)niobium(V) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η5-C5Me5)2NbH3

There total 1 articles about (η5-C5Me5)2NbH3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: (η5-C5Me5)2NbBH4

: 93558-77-1
(η5-C5Me5)2NbH3

Guidance literature:: With H₂; pyridine; In toluene; byproducts: C5H5N*BH3; pyridine was added to a soln. of Nb complex at -196°C, 1 atm of H2 was added, the soln. was warmed to room temp. and stirred for 8 h; filtn., cooling, washing of pink solid (cold petroleum ether), purifiedby repeated recrystn. from octane and petroleum ether; elem. anal.;
DOI:10.1021/om00136a022

Reference yield: 80.0%

: 93558-77-1
(η5-C5Me5)2NbH3

: 5339-11-7
dimethyl-(3-vinyl-phenyl)-amine

: 113628-24-3
endo-(η5-C5Me5)2NbH(CH2=CH-C6H4-m-NMe2)

Guidance literature:: In toluene; heating (air-absence, 80°C, 20 h); solvent removal, addn. of petroleum ether (pptn.), recrystn. (petroleum ether); elem. anal.;
DOI:10.1021/ja00218a023

Reference yield: 80.0%

: 622-97-9,24936-41-2
1-ethenyl-4-methylbenzene

: 93558-77-1
(η5-C5Me5)2NbH3

: 95313-66-9
((CH₃)5C₅)2Nb(CH₂CH(C₆H₄CH₃))(H)

Guidance literature:: In toluene; byproducts: H2, CH3CH3(p-CH3-C6H5); educts (excess of olefin) mixed at -78°C; mixt. warmed to 90°C, stirred for 12 h; soln. filtered, volatiles removed under reduced pressure; crystn. from petroleum ether, elem. anal.;
DOI:10.1021/ja00295a020