tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane
CAS No.:178436-04-9
Molecular Formula:C₃₅H₄₆OSi
Molecular Weight:510.835
Hs Code.:

Synonyms:tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

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Chemical Property of tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

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Technology Process of tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

There total 1 articles about tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 178435-98-8
{(1S,2R,1'R,2'R,1''R,2''R,1'''S,2'''R)-2'''-[(Z)-2-Benzenesulfonyl-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-tert-butyl-diphenyl-silane

: 178436-04-9
tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

Guidance literature:: With naphthalene; lithium; In tetrahydrofuran; at -78 ℃; for 0.1h;
DOI:10.1021/ja961093g

Reference yield:

: 178436-04-9
tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

: 197013-61-9
(2E,4E)-5-{(1R,2S,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-Methyl-cyclopropyl)-vinyl]-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl}-penta-2,4-dienoic acid 4-nitro-phenyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / Bu₄NF / tetrahydrofuran / 2 h / 23 °C

2: 91 percent / tetrapropylammonium perruthenante, NMO, 4A molecular sieves / CH₂Cl₂ / 0.3 h / 23 °C

3: 89 percent / LiN(TMS)2 / tetrahydrofuran / 3 h / -78 - 23 °C

4: 90 percent / LiOH / methanol; H₂O / 48 h / 23 °C

5: 73 percent / DCC, DMAP / CH₂Cl₂ / 24 h / 23 °C

With dmap; lithium hydroxide; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; tetrabutyl ammonium fluoride; dicyclohexyl-carbodiimide; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/ja961093g

Reference yield:

: 178436-04-9
tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane

: 120500-69-8
FR-900848

Guidance literature:: Multi-step reaction with 6 steps

1: 95 percent / Bu₄NF / tetrahydrofuran / 2 h / 23 °C

2: 91 percent / tetrapropylammonium perruthenante, NMO, 4A molecular sieves / CH₂Cl₂ / 0.3 h / 23 °C

3: 89 percent / LiN(TMS)2 / tetrahydrofuran / 3 h / -78 - 23 °C

4: 90 percent / LiOH / methanol; H₂O / 48 h / 23 °C

5: 73 percent / DCC, DMAP / CH₂Cl₂ / 24 h / 23 °C

6: 76 percent / dimethylformamide / 3 h / 23 °C

With dmap; lithium hydroxide; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; tetrabutyl ammonium fluoride; dicyclohexyl-carbodiimide; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/ja961093g