4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate

Base Information

• Chemical Name: 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate
• CAS No.: 1617567-88-0
• Molecular Formula: C₄₄H₆₃BrO₅
• Molecular Weight: 751.885
• Mol file: 1617567-88-0.mol

Synonyms:4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate

Chemical Property of 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate

There total 7 articles about 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butan-1-ol (1617567-87-9) + 4-decyloxybenzoyl chloride (50625-44-0) → 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate (1617567-88-0)

Guidance literature:

With pyridine; dmap; In tetrahydrofuran; at 70 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c4cc02242d

Reference yield:

C29H41BrO4 → 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate (1617567-88-0)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide; ethanol / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere

2: dmap; pyridine / tetrahydrofuran / 16 h / 70 °C / Inert atmosphere

With pyridine; dmap; ethanol; sodium hydroxide; In tetrahydrofuran;

DOI:10.1039/c4cc02242d

Reference yield:

1-bromo dodecane (112-29-8) → 4-({4'-[(11-bromoundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate (1617567-88-0)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 24 h / 80 °C / Inert atmosphere

2: sodium hydroxide; water / ethanol / 12 h / Inert atmosphere; Reflux

3: oxalyl dichloride / toluene / 8 h / Inert atmosphere; Reflux

4: dmap; pyridine / tetrahydrofuran / 16 h / 70 °C / Inert atmosphere

With pyridine; dmap; oxalyl dichloride; water; potassium carbonate; potassium iodide; sodium hydroxide; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide; toluene;

DOI:10.1039/c4cc02242d

upstream raw materials:

methyl 4-hydroxylbenzoate

1-bromo dodecane

p-decyloxybenzoic acid

4-[(4'-hydroxybiphenyl-4-yl)oxy]butyl acetate

Downstream raw materials:

4-({4'-[(11-sulfanylundecyl)oxy]biphenyl-4-yl}oxy)butyl 4-(decyloxy)benzoate