methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside

Base Information

• Chemical Name: methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside
• CAS No.: 72278-25-2
• Molecular Formula: C₁₆H₂₁BrO₆
• Molecular Weight: 389.243
• Mol file: 72278-25-2.mol

Synonyms:methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside

Chemical Property of methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside

There total 2 articles about methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 4,6-O-benzylidene-3-C-methyl-2-O-methyl-α-D-mannopyranoside (26540-49-8,68044-36-0,68044-39-3,68044-50-8,72278-24-1) → methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside (72278-25-2)

Guidance literature:

With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; for 4h; Heating;

DOI:10.1016/S0008-6215(00)84691-1

Reference yield:

→ methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside (72278-25-2)

Guidance literature:

Benzylidenverb.4, NBS;

DOI:10.1246/cl.1979.1263

Reference yield: 81.0%

methyl 4-O-benzoyl-6-bromo-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside (72278-25-2) → methyl 4-O-benzoyl-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside (72278-26-3)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 2h; Heating;

DOI:10.1016/S0008-6215(00)84691-1

upstream raw materials:

methyl 4,6-O-benzylidene-3-C-methyl-2-O-methyl-α-D-mannopyranoside

Downstream raw materials:

methyl 4-O-benzoyl-6-deoxy-3-C-methyl-2-O-methyl-α-D-mannopyranoside