Manganese(II) Hexafluoroacetylacetonate

Base Information

• Chemical Name: Manganese(II) Hexafluoroacetylacetonate
• CAS No.: 19648-86-3
• Molecular Formula: C10H2 F12 Mn O4
• Molecular Weight: 469.04
• Hs Code.: 2914700090
• European Community (EC) Number: 671-075-0
• Mol file: 19648-86-3.mol

Synonyms:Manganese(II) Hexafluoroacetylacetonate;19648-86-3;(Z)-1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate;manganese(2+);hydrate

Chemical Property of Manganese(II) Hexafluoroacetylacetonate

Chemical Property:

• Melting Point: 187 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 52.60000
• Density: g/cm³
• LogP: 4.08980
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 17
• Rotatable Bond Count: 2
• Exact Mass: 486.924754
• Heavy Atom Count: 28
• Complexity: 210

Purity/Quality:

98% ^*data from raw suppliers

Bis(hexafluoroacetylacetonato)manganese(II) Hydrate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(C(F)(F)F)[O-])C(=O)C(F)(F)F.C(=C(C(F)(F)F)[O-])C(=O)C(F)(F)F.O.[Mn+2]
• Isomeric SMILES: C(=C(\[O-])/C(F)(F)F)\C(=O)C(F)(F)F.C(=C(\[O-])/C(F)(F)F)\C(=O)C(F)(F)F.O.[Mn+2]

Technology Process of Manganese(II) Hexafluoroacetylacetonate

There total 3 articles about Manganese(II) Hexafluoroacetylacetonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

manganese(II) chloride tetrahydrate + 1,1,1,5,5,5-hexafluoroacetylacetone (1522-22-1) → manganese(II) hexafluoroacetonylacetonate (19648-86-3)

Guidance literature:

With ammonium hydroxide;

Reference yield:

manganese(II) chloride tetrahydrate + 1,1,1,5,5,5-hexafluoro-4-hydroxy-pent-3-en-2-one (1694-30-0) → manganese(II) hexafluoroacetonylacetonate (19648-86-3)

Guidance literature:

With sodium hydroxide; In water;

DOI:10.1002/chem.201703423

Reference yield:

manganese(II) hexafluoroacetylacetonate dihydrate → manganese(II) hexafluoroacetonylacetonate (19648-86-3)

Guidance literature:

In n-heptane; dihydrate azeotropically dehydrated in n-heptane; cooled to room temp., in soln. obtained;

DOI:10.1246/cl.2006.68

upstream raw materials:

1,1,1,5,5,5-hexafluoro-4-hydroxy-pent-3-en-2-one

1,1,1,5,5,5-hexafluoroacetylacetone

Downstream raw materials:

Mn(hexafluoroacetylacetonate)2(2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy 3-oxide)2

(4'',4'''-di-tert-butyl-2',2'',2'''-trimethoxy(4-(4'-diphenylaminophenyl)pyridine))2Mn(hfac)2