PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)

Base Information

• Chemical Name: PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)
• CAS No.: 1190949-91-7
• Molecular Formula: C₂₇H₂₇ClNO₅PPdS
• Molecular Weight: 650.428
• Mol file: 1190949-91-7.mol

Synonyms:PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)

Chemical Property of PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)

There total 2 articles about PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.3%

2,6-dimethylpyridine (108-48-5) + [(i)Pr2EtNH][PdCl2(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)] (1190949-90-6) → PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato) (1190949-91-7)

Guidance literature:

With NaB(C₆H₃(CF₃)2)4; In dichloromethane; byproducts: NaCl, CH3CH2NH(CH(CH3)2)2(B(C6H3(CF3)2)4); under Ar, Schlenk techniques; addn. of boron compd. and 2,6-lutidine to soln. of Pd complex in CH2Cl2, mixt. stirred at room temp. for 5 h; filtration through Celite, filtrate evapd. under vac., residue washed with hexane and methanol, dried under vac.;

DOI:10.1021/ja9047398

Reference yield:

2-{bis(2-methoxyphenyl)phosphino}benzenesulphonic acid (257290-43-0) → PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato) (1190949-91-7)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: NaB(C₆H₃(CF₃)2)4 / dichloromethane

With NaB(C₆H₃(CF₃)2)4; In dichloromethane;

DOI:10.1021/ja9047398

Reference yield:

PdCl(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato) (1190949-91-7) + triethylaluminum (97-93-8) → PdEt(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato) (1190949-93-9)

Guidance literature:

In hexane; toluene; byproducts: (CH3CH2)2AlCl; under Ar, Schlenk techniques; addn. of soln. of Al compd. in hexane to soln. of Pd complex in toluene, mixt. stirred at room temp. for 3 h; filtration through Celite, filtrate evapd. under vac., extn. with hexane, ppt. filtered off, dried under vac.; contaminated;

DOI:10.1021/ja9047398

upstream raw materials:

2,6-dimethylpyridine

[(i)Pr₂EtNH][PdCl₂(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)]

2-{bis(2-methoxyphenyl)phosphino}benzenesulphonic acid

Downstream raw materials:

PdEt(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)

Pd(n-Pr)(2,6-lutidine)(2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)