(1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆

Base Information

• Chemical Name: (1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆
• CAS No.: 1354573-12-8
• Molecular Formula: C₂₇H₂₅N₈*F₆P
• Molecular Weight: 606.513
• Mol file: 1354573-12-8.mol

Synonyms:(1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆

Chemical Property of (1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆

There total 1 articles about (1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

ammonium hexafluorophosphate + C13H11N2(1+)*Br(1-) + benzyl azide (622-79-7) → (1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF6 (1354573-12-8)

Guidance literature:

C₁₃H₁₁N₂⁽¹⁺⁾*Br^(1-); benzyl azide; With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In water; tert-butyl alcohol; at 60 ℃; for 24h;

ammonium hexafluorophosphate; In methanol; water;

DOI:10.1039/c4dt02986k

Reference yield: 92.0%

(1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF6 (1354573-12-8) + nickel (7440-02-0) → Ni(C7H4N2(CH2C2HN3CH2C6H5)2)2(2+)*2PF6(1-)=(Ni(C7H4N2(CH2C2HN3CH2C6H5)2)2)(PF6)2

Guidance literature:

With air; In acetonitrile; byproducts: H2O; soln. of imidazolium salt in MeCN treated with excess of Raney nickel powder; reacted at 70°C for 2 d in air; cooled to room temp.; filtered through Celite; filtrate concd.; Et2O added to filtrate; elem. anal.;

DOI:10.1021/om200881s

Reference yield: 46.0%

(1,3-bis((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1H-benzo[d]imidazol-2-ylidene)*HPF6 (1354573-12-8) + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) → C81H72Cu3N24(3+)*3F6P(1-)

Guidance literature:

In water; at 100 ℃; for 24h;

DOI:10.1039/c4dt02986k

upstream raw materials:

benzyl azide