meso-Tetratolylporphyrin-Co(II)

Base Information

• Chemical Name: meso-Tetratolylporphyrin-Co(II)
• CAS No.: 19414-65-4
• Molecular Formula: C48H36 Co N4
• Molecular Weight: 727.834
• Mol file: 19414-65-4.mol

Synonyms:Cobalt,[5,10,15,20-tetra-p-tolylporphinato(2-)]- (8CI); Cobalt,[5,10,15,20-tetrakis(4-methylphenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; 21H,23H-Porphine, 5,10,15,20-tetrakis(4-methylphenyl)-, cobaltcomplex; 21H,23H-Porphine, cobalt deriv.;(5,10,15,20-Tetra-p-tolylporphinato)cobalt; (Tetra-p-tolylporphyrinato)cobalt;(meso-Tetra-p-tolylporphinato)cobalt; Cobalt tetra-p-tolylporphyrin;[meso-5,10,15,20-Tetra-p-tolylporphinato(2-)]cobalt

Chemical Property of meso-Tetratolylporphyrin-Co(II)

Chemical Property:

• PSA: 15.88000
• LogP: 7.67140

Purity/Quality:

98%Min ^*data from raw suppliers

5,10,15,20-Tetra(4-methylphenyl)-21H,23H-porphinecobalt 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetratolylporphyrin-Co(II)

There total 13 articles about meso-Tetratolylporphyrin-Co(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → meso-tetratolylporphyrinatocobalt(II) (19414-65-4)

Guidance literature:

In N,N-dimethyl-formamide; for 0.333333h; Reflux;

DOI:10.1021/acs.inorgchem.7b01509

Reference yield: 95.0%

5,10,15,20-tetrakis(4-methylphenyl)porphyrin + cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) → meso-tetratolylporphyrinatocobalt(II) (19414-65-4)

Guidance literature:

In N,N-dimethyl-formamide; reflux for 1 h;

DOI:10.1021/om9705315

Reference yield: 92.0%

5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → meso-tetratolylporphyrinatocobalt(II) (19414-65-4)

Guidance literature:

With cobalt(II) diacetate tetrahydrate; In propionic acid; 1,2-dichloro-benzene; Reflux;

DOI:10.1021/ja205738z

upstream raw materials:

cobalt(II) acetate

sodium tetrahydroborate

N,N,N,N,N,N-hexamethylphosphoric triamide

((C₄H₂NC(p-MeC₆H₄))4)CoBr

Downstream raw materials:

Co(C₁₂H₉N)4O₂

5,10,15,20-tetra-p-tolylporphyrinato(dimethylsulfoxide)cobalt(II)

Co(NC₄H₂CC₆H₄CH₃)4(C₃N₂H₃CH₃)2⁽¹⁺⁾*Cl^(1-)=[Co(NC₄H₂CC₆H₄CH₃)4(C₃N₂H₃CH₃)2]Cl

((C₄H₂NC(p-MeC₆H₄))4)CoBr

Refernces

• 1、 Vaid, Thomas P.. "A porphyrin with a C=C unit at its center". . p. 15838 - 15841. Retrieved 2011.
• 2、 Subedi, Dili R.,Jang, Youngwoo,Ganesan, Ashwin,Schoellhorn, Sydney,Reid, Ryan,Verbeck, Guido F.,D'Souza, Francis. "Donor-acceptor conjugates derived from cobalt porphyrin and fullerene via metal-ligand axial coordination: Formation and excited state charge separation". . p. 533 - 546. Retrieved 2021/04/28.
• 3、 Shen, Hai-Min,Qi, Bei,Hu, Meng-Yun,Liu, Lei,Ye, Hong-Liang,She, Yuan-Bin. "Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C–H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N-Hydroxyphthalimide". . p. 3096 - 3111. Retrieved 2020/04/29.