C₅₄H₆₄O₇Si

Base Information

Chemical Name:C₅₄H₆₄O₇Si
CAS No.:1120309-54-7
Molecular Formula:C₅₄H₆₄O₇Si
Molecular Weight:853.183
Hs Code.:

C<sub>54</sub>H<sub>64</sub>O<sub>7</sub>Si

Synonyms:C₅₄H₆₄O₇Si

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Chemical Property of C₅₄H₆₄O₇Si

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Technology Process of C₅₄H₆₄O₇Si

There total 20 articles about C₅₄H₆₄O₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1120309-21-8
(E)-(1S,4R,5R)-1-((E)-(S)-4-allyloxy-1-ethylbut-2-enyl)-7-( tert-butyldiphenylsilanyloxy)-4-hydroxy-5-methoxymethoxy-4-(2-trityloxyethyl)hept-2-en-1-yl acrylate

: 1120309-23-0
(5S,6S)-6-[(E)-(3R,4R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-4-methoxymethoxy-3-(2-trityloxyethyl)hex-1-en-1-yl]-5-ethyl-5,6-dihydropyran-2-one

: 1120309-54-7
C₅₄H₆₄O₇Si

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 2h; Reflux;
DOI:10.1021/ol8029142

Reference yield:

: 1120308-99-7
(R)-1-(allyloxy)hex-3-yn-2-ol

: 1120309-23-0
(5S,6S)-6-[(E)-(3R,4R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-4-methoxymethoxy-3-(2-trityloxyethyl)hex-1-en-1-yl]-5-ethyl-5,6-dihydropyran-2-one

: 1120309-54-7
C₅₄H₆₄O₇Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: copper(I) bromide; lithium bromide; zinc / tetrahydrofuran; ethylene dibromide; isopropyl alcohol / 18 h / 20 °C / Reflux

2.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C

5.1: isopropylmagnesium chloride / tetrahydrofuran; diethyl ether / -20 - 0 °C

5.2: 1.5 h / -20 °C

6.1: sodium bis(2-methoxyethoxy)aluminium dihydride / diethyl ether; toluene / 6 h / 0 °C

7.1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / -78 °C

7.2: 2 h / -78 °C

8.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; n-butyllithium; potassium tert-butylate; tetrabutyl ammonium fluoride; isopropylmagnesium chloride; N-ethyl-N,N-diisopropylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; copper(I) bromide; lithium bromide; zinc; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; ethylene dibromide; isopropyl alcohol; toluene; 3.1: [2,3]-Wittig rearrangement;
DOI:10.1021/ol8029142

Reference yield:

: 1120309-32-1
(Z)-(R)-1-(allyloxy)hex-3-en-2-ol

: 1120309-23-0
(5S,6S)-6-[(E)-(3R,4R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-4-methoxymethoxy-3-(2-trityloxyethyl)hex-1-en-1-yl]-5-ethyl-5,6-dihydropyran-2-one

: 1120309-54-7
C₅₄H₆₄O₇Si

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C

4.1: isopropylmagnesium chloride / tetrahydrofuran; diethyl ether / -20 - 0 °C

4.2: 1.5 h / -20 °C

5.1: sodium bis(2-methoxyethoxy)aluminium dihydride / diethyl ether; toluene / 6 h / 0 °C

6.1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / -78 °C

6.2: 2 h / -78 °C

7.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; n-butyllithium; potassium tert-butylate; tetrabutyl ammonium fluoride; isopropylmagnesium chloride; N-ethyl-N,N-diisopropylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; toluene; 2.1: [2,3]-Wittig rearrangement;
DOI:10.1021/ol8029142