N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine

Base Information

• Chemical Name: N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine
• CAS No.: 2234-12-0
• Molecular Formula: C₂₆H₂₀N₂
• Molecular Weight: 360.458
• Mol file: 2234-12-0.mol

Synonyms:N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine

Chemical Property of N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine

There total 4 articles about N-[1-Biphenyl-4-yl-meth-(Z)-ylidene]-N'-[1-biphenyl-4-yl-meth-(E)-ylidene]-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

sodium isopropylate (683-60-3) + N′-([1,1′-biphenyl]-4-ylmethylene)-4-methylbenzenesulfonohydrazide (40154-51-6) → biphenyl-4-carboxaldehyde azine (2234-12-0) + 4-isopropoxymethyl-biphenyl

Guidance literature:

sodium isopropylate; N′-([1,1′-biphenyl]-4-ylmethylene)-4-methylbenzenesulfonohydrazide; In isopropyl alcohol; at 50 ℃; for 2h;

With silver nanoparticles; In isopropyl alcohol; for 12h; Reflux;

DOI:10.2174/157017812799303971

Reference yield: 31.0%

biphenyl (92-52-4,1594-86-1) + N,N,N',N'-tetraformylhydrazine (52023-52-6) → biphenyl-4-carboxaldehyde azine (2234-12-0)

Guidance literature:

With aluminium trichloride; In chlorobenzene; at -12 - 18 ℃; for 20h;

Reference yield:

biphenyl-4-yl methanol (3597-91-9) → biphenyl-4-carboxaldehyde azine (2234-12-0)

Guidance literature:

Multi-step reaction with 2 steps

1: nitric acid / 1,4-dioxane / 2 h / 90 °C / Schlenk technique

2: oxidized multiwalled carbon nanotubes / 1,4-dioxane / 3 h / 20 °C

With nitric acid; In 1,4-dioxane;

DOI:10.1016/j.jcat.2022.01.009

upstream raw materials:

biphenyl

N,N,N',N'-tetraformylhydrazine

sodium isopropylate

N′-([1,1′-biphenyl]-4-ylmethylene)-4-methylbenzenesulfonohydrazide

Downstream raw materials:

4,4'-diphenylstilbene

trans-4,4'-diphenylstilbene

p-biphenylcarboxyaldehyde azine-4,4'-bisulfonyl chlride

4-Phenylbenzaldehyde