cis-benzylmanganese tetracarbonyl triphenylphosphine

Base Information

Chemical Name:cis-benzylmanganese tetracarbonyl triphenylphosphine
CAS No.:54834-89-8
Molecular Formula:C₂₉H₂₂MnO₄P
Molecular Weight:520.403
Hs Code.:

Synonyms:cis-benzylmanganese tetracarbonyl triphenylphosphine

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Chemical Property of cis-benzylmanganese tetracarbonyl triphenylphosphine

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Technology Process of cis-benzylmanganese tetracarbonyl triphenylphosphine

There total 4 articles about cis-benzylmanganese tetracarbonyl triphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

: benzylpentacarbonylmanganese

: 3878-44-2
Triphenylphosphine selenide

: 54834-89-8
cis-benzylmanganese tetracarbonyl triphenylphosphine

: 191792-60-6
η(2)-(C,S)-[(2-diphenylselenophosphinyl)phenyl]tetracarbonylmanganese

: 177216-88-5
Mn2(μ-SeCH2Ph)2(CO)8

Guidance literature:: In petroleum ether; N2-atmosphere; refluxing phosphine with slight excess of Mn-complex for 4 h; in air; solvent removal (vac.), dissoln. in CH2Cl2, chromy. (SiO2, EtOAc/petroleum ether=1:3), recrystn. (CHCl3/petroleum ether); elem. anal.;
DOI:10.1016/S0022-328X(96)06835-0

Reference yield:

: 122967-79-7
(η3-C6H5CH2)Mn(CO)4

: 54834-89-8
cis-benzylmanganese tetracarbonyl triphenylphosphine

Guidance literature:: With triphenylphosphine; In not given; Irradiation (UV/VIS); warming up the η3 complex soln. to 200-295°C (Ar); not isolated, IR, (1)HNMR; Kinetics;
DOI:10.1021/ja00157a026

Reference yield:

: benzylpentacarbonylmanganese

: 2Mn*8CO*2(P(C₆H₅)3) = Mn₂(CO)8(P(C₆H₅)3)2

: 54834-89-8
cis-benzylmanganese tetracarbonyl triphenylphosphine

Guidance literature:: With triphenylphosphine; In not given; Irradiation (UV/VIS); soln. of complex and phosphine in alkane soln. irradiated under Ar at 295K with light of 366 nm; main product is the η1-benzyl complex; not isolated, IR;
DOI:10.1021/ja00157a026