(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

Base Information

Chemical Name:(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one
CAS No.:304672-04-6
Molecular Formula:C₃₃H₃₆O₇
Molecular Weight:544.645
Hs Code.:

Synonyms:(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

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Chemical Property of (3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

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Technology Process of (3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

There total 1 articles about (3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 304672-03-5
(4R,5S,6S)-4,5,6-Tris-benzyloxy-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-cyclohex-2-enone

: 304672-04-6
(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

Guidance literature:: With dihydrogen peroxide; potassium carbonate; In tetrahydrofuran; water; at 0 ℃; for 6h;
DOI:10.3987/com-00-8987

Reference yield:

: 304672-04-6
(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

: (4R,5S,6S)-4,5,6-Tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / NaBH₄ / methanol / 0.25 h / -40 °C

2: 98 percent / benzene / 12 h / 80 °C

3: 30 percent / Bu₃SnH; AIBN / benzene / 4 h / 80 °C

4: 87 percent / MnO₂ / CH₂Cl₂ / 45 °C

With manganese(IV) oxide; sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In methanol; dichloromethane; benzene;
DOI:10.3987/com-00-8987

Reference yield:

: 304672-04-6
(3S,4S,5S)-3,4,5-Tris-benzyloxy-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-7-oxa-bicyclo[4.1.0]heptan-2-one

: 304672-05-7
(4R,5S,6R)-4,5,6-Tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-cyclohex-2-enol

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / NaBH₄ / methanol / 0.25 h / -40 °C

2: 98 percent / benzene / 12 h / 80 °C

3: 30 percent / Bu₃SnH; AIBN / benzene / 4 h / 80 °C

With sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In methanol; benzene;
DOI:10.3987/com-00-8987