(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

Base Information

Chemical Name:(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one
CAS No.:1256796-57-2
Molecular Formula:C₂₄H₃₄O₂SSi₂
Molecular Weight:442.77
Hs Code.:

Synonyms:(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

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Chemical Property of (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

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Technology Process of (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

There total 1 articles about (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1256796-56-1
(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol

: 1256796-57-2
(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1039/c0ob00151a

Reference yield: 95.0%

: 1256796-57-2
(6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one

: 1256796-76-5
(5R,6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol

Guidance literature:: (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one; With (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; toluene; at -15 ℃; for 0.25h; Inert atmosphere;

With dimethylsulfide borane complex; In tetrahydrofuran; toluene; at -15 ℃; for 1h; stereoselective reaction; Inert atmosphere;
DOI:10.1039/c0ob00151a