2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin

Base Information

• Chemical Name: 2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin
• CAS No.: 87682-01-7
• Molecular Formula: C₂₈H₃₈O₆S₂
• Molecular Weight: 534.738
• Mol file: 87682-01-7.mol

Synonyms:2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin

Chemical Property of 2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin

There total 1 articles about 2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,6-Dimethylcatechol (2785-78-6) → 2,3,5,6,8,9,11,12,14,15,18,20,25,27-tetradecahydro-22,31-dimethyl-17,28:21,24-diethenocyclotetradeca<3,4-b>-1,4,7,10,13,16,19,26-hexaoxadithiacyclooctadecin (87682-01-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) 85 percent KOH / 1.) THF, RT, 1 h, 2.) reflux 18 h

2: 1.) NBS, benzoyl peroxide, 2.) KOAc / 1.) CCl₄, reflux, 1 h, 2.) AcOH, reflux, 1.5 h

3: 35 percent / HBr / CHCl₃ / 5 h / Ambient temperature

4: 26.9 percent / 85 percent KOH / ethanol; benzene / 72 h

With potassium hydroxide; N-Bromosuccinimide; Perbenzoic acid; hydrogen bromide; potassium acetate; In ethanol; chloroform; benzene;

DOI:10.1021/jo00172a053

upstream raw materials:

3,6-Dimethylcatechol