4-Thioanisolemagnesium bromide

Base Information

Chemical Name:4-Thioanisolemagnesium bromide
CAS No.:18620-04-7
Molecular Formula:C7H7BrMgS
Molecular Weight:227.408
Hs Code.:29309090
European Community (EC) Number:807-344-8
Mol file:18620-04-7.mol

Synonyms:18620-04-7;4-Thioanisolemagnesium bromide;magnesium;methylsulfanylbenzene;bromide;MFCD00672010;(4-(methylthio)phenyl)magnesium bromide;Magnesium,bromo[4-(methylthio)phenyl]-;4-(methylthio)phenylmagnesium bromide;SCHEMBL958355;SSVQCUSLJVVRCA-UHFFFAOYSA-M;4-THIOANISOLEMAGNESIUMBROMIDE;4-methylsulfanylphenylmagnesium bromide;AKOS015909230;4-methylsulfanyl-phenylmagnesium bromide;4-Thioanisolemagnesium bromide, 0.5M THF;4-Thioanisolemagnesium bromide 0.5 M in Tetrahydrofuran;4-Thioanisolemagnesium bromide, 0.5M in tetrahydrofuran;4-(Methylthio)phenylmagnesium bromide, 0.50 M in 2-MeTHF

Suppliers and Price of 4-Thioanisolemagnesium bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4-Thioanisolemagnesium bromide solution 0.5M in THF
50ml
$ 253.00

Rieke Metals
4-(Methylthio)phenylmagnesiumbromide
100mL
$ 349.00

Rieke Metals
4-(Methylthio)phenylmagnesiumbromide
50mL
$ 187.00

American Custom Chemicals Corporation
4-THIOANISOLEMAGNESIUM BROMIDE 95.00%
1L
$ 8085.00

American Custom Chemicals Corporation
4-THIOANISOLEMAGNESIUM BROMIDE 95.00%
500ML
$ 5082.00

American Custom Chemicals Corporation
4-THIOANISOLEMAGNESIUM BROMIDE 95.00%
100ML
$ 2633.40

Total 13 raw suppliers

Chemical Property of 4-Thioanisolemagnesium bromide

Chemical Property:

Boiling Point:65 °C
Flash Point:<1 °F
PSA：25.30000
Density:0.965 g/mL at 25 °C
LogP:3.05430
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:225.93023
Heavy Atom Count:10
Complexity:145

Purity/Quality:

98%Min ^*data from raw suppliers

4-Thioanisolemagnesium bromide solution 0.5M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s): F;C;F+
Hazard Codes:F,C,F+
Statements: 11-14-19-34-12-37-40
Safety Statements: 16-26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CSC1=CC=[C-]C=C1.[Mg+2].[Br-]
Uses 4-Thioanisolemagnesium bromide can be used to prepare:3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.(1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.

Technology Process of 4-Thioanisolemagnesium bromide

There total 2 articles about 4-Thioanisolemagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 20057-77-6
1,2-bis[4-(methylthio)phenyl]disulfane

: 18620-04-7
4-thioanisolemagnesium bromide

Guidance literature:

Reference yield:

: 104-95-0
(4-bromophenyl)thioanisole

: 18620-04-7
4-thioanisolemagnesium bromide

Guidance literature:: With magnesium; In tetrahydrofuran; at 0 ℃;

Reference yield: 95.0%

: 18620-04-7
4-thioanisolemagnesium bromide

: 5896-17-3
2-(phenylmethoxy)benzaldehyde

: 875109-38-9
(2-Benzyloxyphenyl)-(4-methylsulfanylphenyl)methanol

Guidance literature:: 4-thioanisolemagnesium bromide; 2-(phenylmethoxy)benzaldehyde; In tetrahydrofuran; at 0 - 20 ℃; for 2h;

With water; ammonium chloride; In tetrahydrofuran; at 0 ℃;