Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane)

Base Information

• Chemical Name: Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane)
• CAS No.: 85744-48-5
• Molecular Formula: C₃₂H₂₈N₄P₂Pt
• Molecular Weight: 725.629
• Mol file: 85744-48-5.mol

Synonyms:Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane)

Chemical Property of Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane)

Chemical Property:

Purity/Quality:

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Technology Process of Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane)

There total 1 articles about Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + thallium 2,2'-bi-imidazolate → thallium chloride (55172-29-7,7791-12-0) + Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane) (85744-48-5)

Guidance literature:

In dichloromethane; equimolar mixt. Tl2BiIm and PtCl2(dpe) in CH2Cl2 stirred at room temp. for 2 h; TlCl filtered, solvent evapd. partially, ether added; elem. anal.;

DOI:10.1016/S0277-5387(00)83951-0

Reference yield: 88.0%

Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane) (85744-48-5) → (Pt(biimidazol)(1,2-bis(diphenylphosphino)ethane))(ClO4)2

Guidance literature:

With perchloric acid; In dichloromethane; Pt(BiIm)(dpe) in CH2Cl2 treated with 60% HClO4 and stirred at room temp. for 1 h; soln. evapd. partially; elem. anal.;

DOI:10.1016/S0277-5387(00)83951-0

Reference yield: 87.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + Pt(biimidazolate)(1,2-bis-(diphenylphosphino)ethane) (85744-48-5) + silver perchlorate → (Pt2(μ-biimidazolate)(1,2-bis(diphenylphosphino)ethane)2)(ClO4)2 + silver(I) chloride

Guidance literature:

In acetone; equimolar mixt. (Pt(dpe)(Me2CO)2)(ClO4)2 (obtained in situ by reacting PtCl2(dpe) with AgClO4 and subsequent removal AgCl) and Pt(BiIm)(dpe) inacetone stirred at room temp. for 3 h; soln. evapd. partially, ether added; elem. anal.;

DOI:10.1016/S0277-5387(00)83951-0

upstream raw materials:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]