(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

Base Information

Chemical Name:(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine
CAS No.:87974-31-0
Molecular Formula:C₃₂H₃₆N₂O₂P₂
Molecular Weight:542.598
Hs Code.:

Synonyms:(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

Chemical Property:

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Technology Process of (3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

There total 1 articles about (3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 87974-36-5
(3S,4S)-1-<2-(Dimethylamino)ethyl>-3,4-pyrrolidinediol

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 87974-31-0
(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

Guidance literature:: With triethylamine; In tetrahydrofuran; at 0 ℃; for 3h;
DOI:10.1246/bcsj.57.739

Reference yield:

: rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate

: 97-65-4,25119-64-6
2-methylenesuccinic acid

: 87974-31-0
(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

: [Rh(itaconic acid)((3S,4S)-N-[2-(dimethylamino)ethyl]-3,4-bis(diphenylphosphinooxy)pyrrolidine)]BF₄

Guidance literature:: With hydrogen; In methanol; soln. of Rh complex and diphosphinite in MeOH degassed, H2 introduced, stirred at room temp., evacuated, added to substrate under N2, further degassed, stirred at room temp. for 30 min; not isolated; detected by NMR;
DOI:10.1246/bcsj.57.739

Reference yield:

: rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate

: 55065-02-6,64590-80-3,5469-45-4
2-(N-acetylamino)cinnamic acid

: 87974-31-0
(3S,4S)-N-<2-(dimethylamino)ethyl>-3,4-bis(diphenylphosphinoxy)pyrrolidine

: [Rh(α-acetamidocinnamic acid)((3S,4S)-N-[2-(dimethylamino)ethyl]-3,4-bis(diphenylphosphinooxy)pyrrolidine)]BF4

Guidance literature:: With hydrogen; In methanol; soln. of Rh complex and diphosphinite in MeOH degassed, H2 introduced, stirred at room temp., evacuated, added to substrate under N2, further degassed, stirred at room temp. for 30 min; not isolated; detected by NMR;
DOI:10.1246/bcsj.57.739