1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

Base Information

Chemical Name:1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane
CAS No.:152999-82-1
Molecular Formula:C₂₄H₂₁N₃O₅
Molecular Weight:431.448
Hs Code.:

Synonyms:1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

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Chemical Property of 1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

Chemical Property:

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Technology Process of 1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

There total 5 articles about 1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 152999-81-0
1-<<4-(Methoxycarbonyl)phenyl>carbonyl>-5-(2-nitrophenyl)dipyrromethane

: 152999-82-1
1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

Guidance literature:: With sodium tetrahydroborate; In methanol; at 0 ℃; for 0.5h;
DOI:10.1021/jo00077a056

Reference yield:

: 1003-29-8,254729-95-8
2-pyrrole aldehyde

: 152999-82-1
1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

Guidance literature:: Multi-step reaction with 6 steps

1: 80.5 percent / aniline*HCl / methanol / 1 h / Ambient temperature

2: 1.) POCl₃ / 1.) r.t., 7 h, 2.) 1,2-dichloroethane, r.t., 13.5 h

3: 57 percent / NBS / acetone; H₂O / 2.5 h / 0 °C

4: 54 percent / PhLi / tetrahydrofuran; diethyl ether; cyclohexane / 2 h / -100 °C

5: 73 percent / Montmorillonite K-10 clay / CHCl₃ / 50 °C

6: NaBH₄ / methanol / 0.5 h / 0 °C

With sodium tetrahydroborate; N-Bromosuccinimide; Montmorillonite K-10 clay; aniline hydrochloride; phenyllithium; trichlorophosphate; In tetrahydrofuran; methanol; diethyl ether; chloroform; cyclohexane; water; acetone;
DOI:10.1021/jo00077a056

Reference yield:

: 152999-79-6
2-Formyl-5-<4-(methoxycarbonyl)benzoyl>pyrrole

: 152999-82-1
1-<<4-(Methoxycarbonyl)phenyl>hydroxymethyl>-5-(2-nitrophenyl)dipyrromethane

Guidance literature:: Multi-step reaction with 3 steps

1: 54 percent / PhLi / tetrahydrofuran; diethyl ether; cyclohexane / 2 h / -100 °C

2: 73 percent / Montmorillonite K-10 clay / CHCl₃ / 50 °C

3: NaBH₄ / methanol / 0.5 h / 0 °C

With sodium tetrahydroborate; Montmorillonite K-10 clay; phenyllithium; In tetrahydrofuran; methanol; diethyl ether; chloroform; cyclohexane;
DOI:10.1021/jo00077a056