(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

Base Information

Chemical Name:(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide
CAS No.:142404-94-2
Molecular Formula:C₃₃H₄₃NO₄SSi
Molecular Weight:577.86
Hs Code.:

(Z)-1-(tert-butyldiphenylsilyloxy)-7-<N-(4-phenylsulfonylbutylidene)amino>-(Z)-hept-3-ene N-oxide

Synonyms:(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

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Chemical Property of (Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

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Technology Process of (Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

There total 9 articles about (Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 114092-92-1
4-(phenylsulfonyl)butyraldehyde

: N-[(Z)-7-(tert-Butyl-diphenyl-silanyloxy)-hept-4-enyl]-hydroxylamine

: 142404-94-2
(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

Guidance literature:: With sodium sulfate; In dichloromethane; for 12h; 0 deg C to rt;

Reference yield:

: 88158-68-3
4-(tert-butyldiphenylsilyloxy)-1-butyne

: 142404-94-2
(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

Guidance literature:: Multi-step reaction with 6 steps

1: 1a) BuLi, b) tetramethylethylenediamine / 1a) THF, hexane, -5 deg C, 1.5 h, b) rt, 10 min, 2) reflux, 48 h

2: 100 percent / H₂ / Lindlar catalyst / ethyl acetate / 3 h / 760 Torr

3: conc. HCl / acetone; H₂O / 0.5 h

4: 1) NaOAc, 2) NH₂OH*HCl / 1) MeOH, rt, 2) 12 h

5: NaCNBH₃, HCl(pH 3) / methanol / 0.5 h / 0 °C

6: 85 percent / Na₂SO₄ / CH₂Cl₂ / 12 h / 0 deg C to rt

With hydrogenchloride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydroxylamine hydrochloride; hydrogen; sodium acetate; sodium cyanoborohydride; sodium sulfate; Lindlar's catalyst; In methanol; dichloromethane; water; ethyl acetate; acetone;

Reference yield:

: 142404-91-9
2-<6-(tert-butyldiphenylsilyloxy)hex-3-ynyl>-1,3-dioxolane

: 142404-94-2
(Z)-1-(tert-butyldiphenylsilyloxy)-7--(Z)-hept-3-ene N-oxide

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / H₂ / Lindlar catalyst / ethyl acetate / 3 h / 760 Torr

2: conc. HCl / acetone; H₂O / 0.5 h

3: 1) NaOAc, 2) NH₂OH*HCl / 1) MeOH, rt, 2) 12 h

4: NaCNBH₃, HCl(pH 3) / methanol / 0.5 h / 0 °C

5: 85 percent / Na₂SO₄ / CH₂Cl₂ / 12 h / 0 deg C to rt

With hydrogenchloride; hydroxylamine hydrochloride; hydrogen; sodium acetate; sodium cyanoborohydride; sodium sulfate; Lindlar's catalyst; In methanol; dichloromethane; water; ethyl acetate; acetone;