Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)-

Base Information

• Chemical Name: Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)-
• CAS No.: 17883-25-9
• Molecular Formula: C₈H₂₅NOSi₃
• Molecular Weight: 235.549
• Hs Code.: 2931900090
• Mol file: 17883-25-9.mol

Synonyms:3-Oxa-5-aza-2,4,6-trisilaheptane,2,2,4,4,6,6-hexamethyl- (8CI); Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)-(9CI); Disiloxane, pentamethyl[(trimethylsilyl)amino]- (6CI)

Chemical Property of Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)-

Chemical Property:

• PSA: 21.26000
• LogP: 3.35510

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)-

There total 4 articles about Disiloxanamine, 1,1,3,3,3-pentamethyl-N-(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

O-(dimethylsilyl)-N,N-bis(trimethylsilyl)hydroxylamine (61012-53-1) → 1,1,1,3,3-pentamethyl-3-[(trimethylsilyl)amino]-1,3-disiloxane (17883-25-9)

Guidance literature:

for 72h; Heating;

DOI:10.1002/1099-0682(200203)2002:4<876::AID-EJIC876>3.0.CO;2-2

Reference yield:

N,O-Bis-(trimethylsilyl)-N-dimethylsilyl-hydroxylamin (61012-56-4) → 1,1,1,3,3-pentamethyl-3-[(trimethylsilyl)amino]-1,3-disiloxane (17883-25-9)

Guidance literature:

(thermolysis);

DOI:10.1021/ja00434a036

Reference yield:

N,N-bis(trimethylsilyl)hydroxylamine → 1,1,1,3,3-pentamethyl-3-[(trimethylsilyl)amino]-1,3-disiloxane (17883-25-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: nBuLi in hexane / 2 h / Heating

1.2: 73 percent / hexane / 20 °C

2.1: 82 percent / 72 h / Heating

With n-butyllithium;

DOI:10.1002/1099-0682(200203)2002:4<876::AID-EJIC876>3.0.CO;2-2

upstream raw materials:

O-(dimethylsilyl)-N,N-bis(trimethylsilyl)hydroxylamine

N,O-Bis-(trimethylsilyl)-N-dimethylsilyl-hydroxylamin

Refernces