(3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid

Base Information

• Chemical Name: (3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid
• CAS No.: 173355-98-1
• Molecular Formula: C₁₅H₂₈O₈
• Molecular Weight: 336.383
• Mol file: 173355-98-1.mol

Synonyms:(3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid

Chemical Property of (3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid

There total 1 articles about (3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-5-n-butyl-4-methyl-4,5-dihydro-2(3H)-furanone (89163-43-9,39212-23-2,39638-67-0,55013-32-6,80041-00-5,80041-01-6,99530-35-5,105015-53-0,105119-22-0) → (3S,4S)-3-methyl-4-O-β-D-glucopyranosyloctanoic acid (173355-98-1)

Guidance literature:

Multi-step reaction with 4 steps

1.1: KOH / methanol / 16 h / 20 °C

2.1: 1.59 g / dimethylformamide / 16 h / 20 °C

3.1: AgOTf; 2,6-lutidine / CH₂Cl₂ / 16 h / 20 °C

4.1: NaOMe / methanol / 16 h / 20 °C

4.2: 56 percent / aq. KOH / 16 h / 20 °C

With 2,6-dimethylpyridine; potassium hydroxide; sodium methylate; silver trifluoromethanesulfonate; In methanol; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1016/j.tet.2004.05.070

upstream raw materials:

cis-5-n-butyl-4-methyl-4,5-dihydro-2(3H)-furanone