(S)-1-(4-nitrophenyl)allyl carbamate

Base Information

Chemical Name:(S)-1-(4-nitrophenyl)allyl carbamate
CAS No.:914646-14-3
Molecular Formula:C₁₀H₁₀N₂O₄
Molecular Weight:222.2
Hs Code.:

Synonyms:(S)-1-(4-nitrophenyl)allyl carbamate

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Chemical Property of (S)-1-(4-nitrophenyl)allyl carbamate

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Technology Process of (S)-1-(4-nitrophenyl)allyl carbamate

There total 3 articles about (S)-1-(4-nitrophenyl)allyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 3019-71-4
Trichloroacetyl isocyanate

: 914646-11-0
(S)-1-(4-nitrophenyl)-2-propen-1-ol

: 914646-14-3
(S)-1-(4-nitrophenyl)allyl carbamate

Guidance literature:: Trichloroacetyl isocyanate; (S)-1-(4-nitrophenyl)-2-propen-1-ol; In dichloromethane; at 0 - 25 ℃; for 2h;

With potassium carbonate; In methanol; water; at 0 - 25 ℃; for 18h;
DOI:10.1016/j.tet.2006.08.019

Reference yield:

: 555-16-8
4-nitrobenzaldehdye

: 914646-14-3
(S)-1-(4-nitrophenyl)allyl carbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: ZnCl₂ / tetrahydrofuran / 18 h / 55 °C

1.2: 68 percent / tetrahydrofuran / -78 - 25 °C

2.1: 44 percent / Ti(O-iPr)4; (+)-diisopropyl tartrate; tert-butyl hydroperoxide / molecular sieves 4 Angstroem / CH₂Cl₂ / 14 h / -20 °C

3.1: CH₂Cl₂ / 2 h / 0 - 25 °C

3.2: 90 percent / potassium carbonate / methanol; H₂O / 18 h / 0 - 25 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; zinc(II) chloride; 4 A molecular sieve; In tetrahydrofuran; dichloromethane; 2.1: Sharpless asymmetric epoxidation;
DOI:10.1016/j.tet.2006.08.019

Reference yield:

: 123232-63-3
1-(4-nitrophenyl)-prop-2-en-1-ol

: 914646-14-3
(S)-1-(4-nitrophenyl)allyl carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 44 percent / Ti(O-iPr)4; (+)-diisopropyl tartrate; tert-butyl hydroperoxide / molecular sieves 4 Angstroem / CH₂Cl₂ / 14 h / -20 °C

2.1: CH₂Cl₂ / 2 h / 0 - 25 °C

2.2: 90 percent / potassium carbonate / methanol; H₂O / 18 h / 0 - 25 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; 4 A molecular sieve; In dichloromethane; 1.1: Sharpless asymmetric epoxidation;
DOI:10.1016/j.tet.2006.08.019