1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Base Information

• Chemical Name: 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
• CAS No.: 114988-18-0
• Molecular Formula: C₂₁H₂₆O₁₁
• Molecular Weight: 454.431
• Mol file: 114988-18-0.mol

Synonyms:1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Chemical Property of 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

There total 4 articles about 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,5-tetra-O-acetyl-D-glucopyranose (3947-62-4,6207-76-7,19235-21-3,22554-70-7,22860-22-6,47339-09-3,57884-82-9,62057-79-8,70191-05-8,109525-54-4,140147-37-1,10343-06-3) + 3-methoxyphenylboronic acid (10365-98-7,1107579-37-2) → 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside (96243-37-7) + 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (114988-18-0)

Guidance literature:

3-methoxyphenylboronic acid; With pyridine; copper(II) acetate monohydrate; In 1,2-dichloro-ethane; for 0.0833333h; Molecular sieve;

2,3,4,5-tetra-O-acetyl-D-glucopyranose; In 1,2-dichloro-ethane; at 20 ℃; for 24h; Overall yield = 77 percent; Overall yield = 175 mg; Molecular sieve;

DOI:10.1021/acs.joc.9b01218

Reference yield:

O-methylresorcine (150-19-6) + β-D-glucose pentaacetate (604-69-3) → 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (114988-18-0)

Guidance literature:

With toluene-4-sulfonic acid;

Reference yield:

O-methylresorcine (150-19-6) + β-D-glucose pentaacetate (604-69-3) → 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside (96243-37-7) + 1-O-(3′-methoxyphenyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (114988-18-0)

Guidance literature:

In benzene; for 0.5h; Heating;

upstream raw materials:

O-methylresorcine

β-D-glucose pentaacetate

2,3,4,5-tetra-O-acetyl-D-glucopyranose

3-methoxyphenylboronic acid

Downstream raw materials:

(3-methoxy-phenyl)-β-D-glucopyranoside