tris(2,6-diphenylbenzyl)silyl glyoxylate

Base Information

• Chemical Name: tris(2,6-diphenylbenzyl)silyl glyoxylate
• CAS No.: 525594-27-8
• Molecular Formula: C₅₉H₄₆O₃Si
• Molecular Weight: 831.098
• Mol file: 525594-27-8.mol

Synonyms:tris(2,6-diphenylbenzyl)silyl glyoxylate

Chemical Property of tris(2,6-diphenylbenzyl)silyl glyoxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(2,6-diphenylbenzyl)silyl glyoxylate

There total 2 articles about tris(2,6-diphenylbenzyl)silyl glyoxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C60H48O2Si → tris(2,6-diphenylbenzyl)silyl glyoxylate (525594-27-8)

Guidance literature:

C₆₀H₄₈O₂Si; With ozone; In dichloromethane;

With dimethylsulfide; In dichloromethane;

DOI:10.1016/S0040-4039(02)02557-1

Reference yield:

tris(2,6-diphenylbenzyl)silyl bromide (308336-00-7) → tris(2,6-diphenylbenzyl)silyl glyoxylate (525594-27-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 95 percent / AgOTf / CH₂Cl₂

2.1: O₃ / CH₂Cl₂

2.2: 99 percent / Me₂S / CH₂Cl₂

With silver trifluoromethanesulfonate; ozone; In dichloromethane;

DOI:10.1016/S0040-4039(02)02557-1

Reference yield: 99.0%

1-(Trimethylsilyloxy)cyclohexene (6651-36-1) + tris(2,6-diphenylbenzyl)silyl glyoxylate (525594-27-8) → C65H56O4Si

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.5h;

DOI:10.1016/S0040-4039(02)02557-1

upstream raw materials:

tris(2,6-diphenylbenzyl)silyl bromide

Downstream raw materials:

C₆₅H₅₂O₃Si