benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

Base Information

• Chemical Name: benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)
• CAS No.: 727722-21-6
• Molecular Formula: C₄₄H₃₈P₂Pd
• Molecular Weight: 735.153
• Mol file: 727722-21-6.mol

Synonyms:benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

Chemical Property of benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

There total 3 articles about benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.7%

bromo(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium (351531-26-5) + phenylmagnesium bromide (1589-82-8) → benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran) (727722-21-6)

Guidance literature:

In diethyl ether; toluene; under N2; Pd complex suspended in toluene; C6H5CH2MgBr (1 equiv.) in Et2O added dropwise under stirring; stirred at room temp. for 5 min; filtered through Celite; filtrate layered with pentane at -35°C; elem. anal.;

DOI:10.1021/om049726k

Reference yield:

o-phenylenebis(diphenylphosphine) (13991-08-7) → benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran) (727722-21-6)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: toluene; diethyl ether

In diethyl ether; toluene; benzene;

DOI:10.1021/om049726k

Reference yield:

2-methylphenyl bromide (95-46-5) → benzyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran) (727722-21-6)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: toluene; diethyl ether

In diethyl ether; toluene; benzene;

DOI:10.1021/om049726k

upstream raw materials:

bromo(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium

phenylmagnesium bromide

o-phenylenebis(diphenylphosphine)

2-methylphenyl bromide

Downstream raw materials:

bis(1,2-bis(diphenylphosphino)benzene)palladium

2-benzyltoluene