Technology Process of C14H16O
There total 3 articles about C14H16O which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); triethylaluminum;
In
hexane; 1,2-dichloro-ethane;
at 0 - 25 ℃;
for 2h;
Inert atmosphere;
DOI:10.1021/ol4006689
- Guidance literature:
-
Multi-step reaction with 3 steps
1: trans-1,2-Diaminocyclohexane; tin(IV) chloride; bis-trimethylsilanyl peroxide / dichloromethane / 24 h / 25 °C / Inert atmosphere; Molecular sieve
2: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere
3: tetrakis(triphenylphosphine) palladium(0); triethylaluminum / 1,2-dichloro-ethane; hexane / 2 h / 0 - 25 °C / Inert atmosphere
With
N,N,N,N,N,N-hexamethylphosphoric triamide; tetrakis(triphenylphosphine) palladium(0); bis-trimethylsilanyl peroxide; trans-1,2-Diaminocyclohexane; triethylaluminum; tin(IV) chloride; potassium hexamethylsilazane;
In
tetrahydrofuran; hexane; dichloromethane; 1,2-dichloro-ethane; toluene;
1: |Baeyer-Villiger Ketone Oxidation;
DOI:10.1021/ol4006689
- Guidance literature:
-
Multi-step reaction with 2 steps
1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere
2: tetrakis(triphenylphosphine) palladium(0); triethylaluminum / 1,2-dichloro-ethane; hexane / 2 h / 0 - 25 °C / Inert atmosphere
With
N,N,N,N,N,N-hexamethylphosphoric triamide; tetrakis(triphenylphosphine) palladium(0); triethylaluminum; potassium hexamethylsilazane;
In
tetrahydrofuran; hexane; 1,2-dichloro-ethane; toluene;
DOI:10.1021/ol4006689