Technology Process of 1-phenyl-1,12-dicarba-closo-dodecaborane
There total 5 articles about 1-phenyl-1,12-dicarba-closo-dodecaborane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-BuLi; N-methylpyrrolidone;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; hexane;
(N2); stirring carborane, BuLi and CuCl (1 h, room temp.), addn. of other educts and cat., stirring (18 h, 100°C); extn. (diethylether), washing (water), drying (MgSO4), chromy. (silica, hexane);
DOI:10.1021/ja963331d
- Guidance literature:
-
With
pyridine; n-butyllithium; copper(l) chloride;
In
1,2-dimethoxyethane; hexane;
to soln. p-carborane in DME soln. n-BuLi in hexane was added at 0°C under Ar and stirred for 30 min, CuCl was added and stirred at room temp. for 2 h, pyridine and iodobenzene were added and refluxed for 8 h; react. mixt. was cooled, soln. was filtered, washed with 2 N HCl, water,and brine, dried over MgSO4 and concd., chromy. on silica (EtOAc-n-hexa ne 1:10);
DOI:10.1021/ic0509736
- Guidance literature:
-
With
n-BuLi; N-methylpyrrolidone;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; hexane;
(N2); stirring carborane, BuLi and CuCl (1 h, room temp.), addn. of other educts and cat., stirring (16 h, 100°C); extn. (toluene), washing (brine), drying (MgSO4), crystn. (hexane/toluene); elem. anal.;
DOI:10.1021/ja963331d
