C₆₃H₇₂O₁₁Si

Base Information

• Chemical Name: C₆₃H₇₂O₁₁Si
• CAS No.: 532929-28-5
• Molecular Formula: C₆₃H₇₂O₁₁Si
• Molecular Weight: 1033.34
• Mol file: 532929-28-5.mol

Synonyms:C₆₃H₇₂O₁₁Si

Chemical Property of C₆₃H₇₂O₁₁Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₃H₇₂O₁₁Si

There total 10 articles about C₆₃H₇₂O₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

phenyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside (62774-33-8) + 1-(tert-butyl-diphenyl-silanyloxy)-tridecan-3-ol (532929-22-9) → C63H72O11Si (532929-28-5)

Guidance literature:

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In dichloromethane; at -15 ℃;

DOI:10.1021/ol034338k

Reference yield:

10-Undecenal (112-45-8) → C63H72O11Si (532929-28-5)

Guidance literature:

Multi-step reaction with 10 steps

1.1: NaH / tetrahydrofuran / 0 °C

2.1: i-Bu₂AlH / CH₂Cl₂ / -78 °C

3.1: 82 percent / (-)-diethyl tartrate; titanium(IV) isopropoxide; t-butyl hydroperoxide / molecular sieves 4 Angstroem / CH₂Cl₂ / -23 °C

4.1: Red-Al / tetrahydrofuran / 0 - 20 °C

4.2: 76 percent / NaIO₄ / CH₂Cl₂; acetone; H₂O

5.1: 99 percent / imidazole / dimethylformamide / 0 °C

6.1: 2,6-lutidine / CH₂Cl₂ / 0 °C

7.1: 18-crown-6 / CH₂Cl₂ / 80 °C

8.1: K₂CO₃ / methanol / 20 °C

9.1: 99 percent / H₂ / Pd/C / ethyl acetate / 20 °C

10.1: 84 percent / N-iodosuccinimide; trifluoromethanesulfonic acid; molecular sieves 4 Angstroem / CH₂Cl₂ / -15 °C

With 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; N-iodo-succinimide; 18-crown-6 ether; trifluorormethanesulfonic acid; 4 A molecular sieve; hydrogen; sodium hydride; diisobutylaluminium hydride; potassium carbonate; (-)-diethyl tartrate; sodium bis(2-methoxyethoxy)aluminium dihydride; palladium on activated charcoal; 4 A molecular sieve; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Wittig reaction / 3.1: Sharpless epoxidation;

DOI:10.1021/ol034338k

Reference yield:

ethyl (E)-trideca-2,12-dienoate (148118-58-5) → C63H72O11Si (532929-28-5)

Guidance literature:

Multi-step reaction with 9 steps

1.1: i-Bu₂AlH / CH₂Cl₂ / -78 °C

2.1: 82 percent / (-)-diethyl tartrate; titanium(IV) isopropoxide; t-butyl hydroperoxide / molecular sieves 4 Angstroem / CH₂Cl₂ / -23 °C

3.1: Red-Al / tetrahydrofuran / 0 - 20 °C

3.2: 76 percent / NaIO₄ / CH₂Cl₂; acetone; H₂O

4.1: 99 percent / imidazole / dimethylformamide / 0 °C

5.1: 2,6-lutidine / CH₂Cl₂ / 0 °C

6.1: 18-crown-6 / CH₂Cl₂ / 80 °C

7.1: K₂CO₃ / methanol / 20 °C

8.1: 99 percent / H₂ / Pd/C / ethyl acetate / 20 °C

9.1: 84 percent / N-iodosuccinimide; trifluoromethanesulfonic acid; molecular sieves 4 Angstroem / CH₂Cl₂ / -15 °C

With 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; N-iodo-succinimide; 18-crown-6 ether; trifluorormethanesulfonic acid; 4 A molecular sieve; hydrogen; diisobutylaluminium hydride; potassium carbonate; (-)-diethyl tartrate; sodium bis(2-methoxyethoxy)aluminium dihydride; palladium on activated charcoal; 4 A molecular sieve; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 2.1: Sharpless epoxidation;

DOI:10.1021/ol034338k

upstream raw materials:

phenyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside

1-(tert-butyl-diphenyl-silanyloxy)-tridecan-3-ol

10-Undecenal

ethyl (E)-trideca-2,12-dienoate