methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

Base Information

Chemical Name:methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate
CAS No.:1289560-52-6
Molecular Formula:C₂₃H₁₉NO₅S₂
Molecular Weight:453.54
Hs Code.:

Synonyms:methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

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Chemical Property of methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

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Technology Process of methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

There total 5 articles about methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 1289560-23-1
2-{2-[(E)-2-(phenylsulfinyl)vinyl]phenylsulfinyl}pyridine

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 1289560-52-6
methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

Guidance literature:: With [bis(acetoxy)iodo]benzene; palladium diacetate; In 1,2-dichloro-ethane; at 110 ℃; for 20h; Inert atmosphere;
DOI:10.1002/chem.201003633

Reference yield:

: 109-04-6
2-bromo-pyridine

: 1289560-52-6
methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / dimethyl sulfoxide / 18 h / 110 °C / Inert atmosphere

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C / Inert atmosphere

3: dipotassium peroxodisulfate; palladium diacetate / 1,2-dichloro-ethane / 20 h / 110 °C / Inert atmosphere

4: [bis(acetoxy)iodo]benzene; palladium diacetate / 1,2-dichloro-ethane / 20 h / 110 °C / Inert atmosphere

With dipotassium peroxodisulfate; [bis(acetoxy)iodo]benzene; palladium diacetate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; dimethyl sulfoxide; 1,2-dichloro-ethane;
DOI:10.1002/chem.201003633

Reference yield:

: 3111-54-4
2-phenylsulfanylpyridine

: 1289560-52-6
methyl 3-{3-[(E)-2-(phenylsulfonyl)vinyl]-2-[(2-pyridyl)sulfinyl]}acrylate

Guidance literature:: Multi-step reaction with 3 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C / Inert atmosphere

2: dipotassium peroxodisulfate; palladium diacetate / 1,2-dichloro-ethane / 20 h / 110 °C / Inert atmosphere

3: [bis(acetoxy)iodo]benzene; palladium diacetate / 1,2-dichloro-ethane / 20 h / 110 °C / Inert atmosphere

With dipotassium peroxodisulfate; [bis(acetoxy)iodo]benzene; palladium diacetate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/chem.201003633