Technology Process of C36H66O7Si2
There total 5 articles about C36H66O7Si2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
at 0 ℃;
for 1h;
Molecular sieve;
Inert atmosphere;
DOI:10.1039/c2ob25100k
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: triethylamine; (-)-diisopinocamphenylborane chloride / diethyl ether / 1 h / -78 - 0 °C / Inert atmosphere
1.2: 17 h / -78 - -20 °C / Inert atmosphere
2.1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / 21 h / -30 - -20 °C / Inert atmosphere
3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 0 °C / Molecular sieve; Inert atmosphere
With
acetic acid; triethylamine; (-)-diisopinocamphenylborane chloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tetramethylammonium triacetoxyborohydride;
In
diethyl ether; dichloromethane; acetonitrile;
1.1: Aldol condensation / 1.2: Aldol condensation;
DOI:10.1039/c2ob25100k
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: ozone / dichloromethane / -78 °C / Inert atmosphere
1.2: 4 h / -78 - 20 °C / Inert atmosphere
2.1: triethylamine; (-)-diisopinocamphenylborane chloride / diethyl ether / 1 h / -78 - 0 °C / Inert atmosphere
2.2: 17 h / -78 - -20 °C / Inert atmosphere
3.1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / 21 h / -30 - -20 °C / Inert atmosphere
4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 0 °C / Molecular sieve; Inert atmosphere
With
ozone; acetic acid; triethylamine; (-)-diisopinocamphenylborane chloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tetramethylammonium triacetoxyborohydride;
In
diethyl ether; dichloromethane; acetonitrile;
2.1: Aldol condensation / 2.2: Aldol condensation;
DOI:10.1039/c2ob25100k
