(Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene))

Base Information

• Chemical Name: (Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene))
• CAS No.: 113087-95-9
• Molecular Formula: 2C₂₄H₂₀P*C₅₃H₅₀Fe₄S₁₄
• Molecular Weight: 2038.09

Synonyms:(Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene))

Chemical Property of (Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene))

Chemical Property:

Purity/Quality:

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Technology Process of (Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene))

There total 4 articles about (Ph₄P)2(Fe₄S₄(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Ph4P)2{Fe4S4(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)Cl} (113087-96-0) + sodium thioethylate (811-51-8) → (Ph4P)2(Fe4S4(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)) (113087-95-9)

Guidance literature:

In dimethylsulfoxide-d6; N2; 1.05-1.10 equivalent of ligand added to soln. of Fe cluster, reaction was immediate; not isolated, product identity established by (1)H NMR spectroscopy;

Reference yield:

(Ph4P)2{Fe4S4(SEt)4} + 1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene (107540-22-7) → (Ph4P)2(Fe4S4(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)) (113087-95-9)

Guidance literature:

In N,N-dimethyl-formamide; components mixed and stirred under dynamic vacuum for 3 h; formed salt isolated and recrystallized from acetonitrile;

DOI:10.1021/ja00216a023

Reference yield:

[Fe4S4(SEt)4](2-) (113087-97-1) + 1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene (107540-22-7) → (Ph4P)2(Fe4S4(SEt)(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)) (113087-95-9)

Guidance literature:

In acetonitrile; reaction (1)H-NMR spectroscopically monitored; quantitative reaction;

DOI:10.1021/ja00216a023

upstream raw materials:

(Ph₄P)2{Fe₄S₄(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)Cl}

sodium thioethylate

1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene

[Fe₄S₄(SEt)4]^(2-)

Downstream raw materials:

(Ph₄P)2{Fe₄S₄(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene)Cl}

Fe₄S₄C₅₁H₄₅S₁₀(C₆H₃Cl₂)^(2-)

Fe₄S₄C₅₁H₄₅S₁₀C₆H₄Br^(2-)

ditrityl disulfide

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