(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

Base Information

Chemical Name:(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol
CAS No.:173656-64-9
Molecular Formula:C₃₅H₄₈O₆Si
Molecular Weight:592.848
Hs Code.:

Synonyms:(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

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Chemical Property of (3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

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Technology Process of (3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

There total 12 articles about (3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 173656-68-3
(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-1-tetrahydropyranyloxy-tetradeca-3,10,12-triene

: 173656-64-9
(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

Guidance literature:: With pyridinium p-toluenesulfonate; In isopropyl alcohol; at 80 ℃; for 1h;
DOI:10.1016/S0040-4039(00)79137-4

Reference yield:

: 144344-22-9
Methanesulfonic acid (Z)-4-methyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-enyl ester

: 173656-64-9
(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH, 2.) KI / 1.) DMF, 1 h, 35-40 deg C, 2.) DMF, THF, 70 deg C, 12 h

2: 78 percent / pyridinium p-toluenesulfonate / propan-2-ol / 1 h / Heating

With pyridinium p-toluenesulfonate; sodium hydride; potassium iodide; In isopropyl alcohol;

Reference yield:

: 173536-84-0
(E,E)-8-tert-butyldiphenylsiloxy-1,1-bis(methoxycarbonyl)-4,6-octadiene

: 173656-64-9
(3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH, 2.) KI / 1.) DMF, 1 h, 35-40 deg C, 2.) DMF, THF, 70 deg C, 12 h

2: 78 percent / pyridinium p-toluenesulfonate / propan-2-ol / 1 h / Heating

With pyridinium p-toluenesulfonate; sodium hydride; potassium iodide; In isopropyl alcohol;