[(C₅H₅)Co(CO)(CH₃)]2

Base Information

• Chemical Name: [(C₅H₅)Co(CO)(CH₃)]2
• CAS No.: 61276-02-6
• Molecular Formula: C₁₄H₁₆Co₂O₂
• Molecular Weight: 334.266
• Mol file: 61276-02-6.mol

Synonyms:[(C₅H₅)Co(CO)(CH₃)]2

Chemical Property of [(C₅H₅)Co(CO)(CH₃)]2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(C₅H₅)Co(CO)(CH₃)]2

There total 1 articles about [(C₅H₅)Co(CO)(CH₃)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

Na{Co2(CO)2(η-C5H5)2} → dicarbonylcyclopentadienylcobalt (12078-25-0,12078-23-8) + [(C5H5)Co(CO)(CH3)]2 (61276-02-6)

Guidance literature:

With methyl iodide; In tetrahydrofuran; Co-complex was suspended in THF and CH3I was added with stirring, mixt.was allowed to stir for 5 min at room temp., petroleum ether was added under N2; filtered, solvent was removed under vac., solid was dissolved in benzene and applied to silica gel-benzene column, eluted, solvent was removed;elem. anal.;

DOI:10.1021/ja00336a026

Reference yield:

[(C5H5)Co(CO)(CH3)]2 (61276-02-6) → dicarbonylcyclopentadienylcobalt (12078-25-0,12078-23-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran-d8; benzene; Co-complex was placed in NMR tube, THF-d8 and benzene were distilled onto the sample under vac., tube was sealed under CO (3 atm, at 25°C), allowed to thaw at -78°C, reaction was allowed to proceed at room temp.; monitored by NMR;

DOI:10.1021/ja00336a026

Reference yield:

[(C5H5)Co(CO)(CH3)]2 (61276-02-6) + [(C5H5)Co(CO)(CH3CH2)]2 (73411-69-5) → dicarbonylcyclopentadienylcobalt (12078-25-0,12078-23-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran-d8; benzene; (CpCo(CO)(CH3))2 and (CpCo(CO)(CH3CH2))2 were placed in NMR tube, THF-d8 and benzene were distilled into the tube, tube was sealed under CO (3 atm, 25°C), tube was thawed at -78°C; monitored by NMR;

DOI:10.1021/ja00336a026

Downstream raw materials:

dicarbonylcyclopentadienylcobalt

(C₅H₅)Co(CO)(CF₃CH₂)(CH₃)