(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Base Information

Chemical Name:(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate
CAS No.:1271192-93-8
Molecular Formula:C₁₆H₁₄F₃IO₄S
Molecular Weight:486.25
Hs Code.:

Synonyms:(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Chemical Property:

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Technology Process of (Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

There total 5 articles about (Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: C₁₅H₁₅IO₂

: 1271192-93-8
(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: With pyridine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1021/ol2003308

Reference yield:

: 591-50-4
iodobenzene

: 1271192-93-8
(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / acetonitrile / 20 °C / Inert atmosphere

2.1: Red-Al / tetrahydrofuran; toluene / 0 °C

2.2: -78 - 0 °C

3.1: pyridine; phosphorus tribromide / diethyl ether / 0 - 20 °C

4.1: N-benzyl-trimethylammonium hydroxide / methanol; water / 20 °C

5.1: pyridine / dichloromethane / -78 - 20 °C

With pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; phosphorus tribromide; N-benzyl-trimethylammonium hydroxide; triethylamine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ol2003308

Reference yield:

: 1504-58-1
3-Phenyl-2-propyn-1-ol

: 1271192-93-8
(Z)-2-(3-iodo-3-phenylallyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: Red-Al / tetrahydrofuran; toluene / 0 °C

1.2: -78 - 0 °C

2.1: pyridine; phosphorus tribromide / diethyl ether / 0 - 20 °C

3.1: N-benzyl-trimethylammonium hydroxide / methanol; water / 20 °C

4.1: pyridine / dichloromethane / -78 - 20 °C

With pyridine; phosphorus tribromide; N-benzyl-trimethylammonium hydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; toluene;
DOI:10.1021/ol2003308