C₅₃H₁₀₂O₅Si₃

Base Information

Chemical Name:C₅₃H₁₀₂O₅Si₃
CAS No.:1337879-22-7
Molecular Formula:C₅₃H₁₀₂O₅Si₃
Molecular Weight:903.646
Hs Code.:

C<sub>53</sub>H<sub>102</sub>O<sub>5</sub>Si<sub>3</sub>

Synonyms:C₅₃H₁₀₂O₅Si₃

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Chemical Property of C₅₃H₁₀₂O₅Si₃

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Technology Process of C₅₃H₁₀₂O₅Si₃

There total 8 articles about C₅₃H₁₀₂O₅Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1337879-12-5
(4R,7S,8S)-4,7,8-tris(tert-butyldimethylsilanyloxy)octadec-1-ene

: 261178-56-7
benzyl 11-dodecenoate

: 1337879-22-7
C₅₃H₁₀₂O₅Si₃

Guidance literature:: With Grubbs catalyst first generation; In dichloromethane; for 4h; Inert atmosphere; Reflux;
DOI:10.1016/j.tet.2011.07.085

Reference yield:

: 1337879-20-5
(4S,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)pentadecan-1-ol

: 1337879-22-7
C₅₃H₁₀₂O₅Si₃

Guidance literature:: Multi-step reaction with 4 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere

1.2: 0.75 h / -78 - 20 °C / Inert atmosphere

2.1: tetrahydrofuran; diethyl ether / 1 h / -78 °C

2.2: 20 °C

3.1: 2,6-dimethylpyridine / dichloromethane / 2 h / 20 °C / Cooling with ice; Inert atmosphere

4.1: Grubbs catalyst first generation / dichloromethane / 4 h / Inert atmosphere; Reflux

With 2,6-dimethylpyridine; Grubbs catalyst first generation; oxalyl dichloride; dimethyl sulfoxide; In tetrahydrofuran; diethyl ether; dichloromethane; 1.1: Swern oxidation / 1.2: Swern oxidation;
DOI:10.1016/j.tet.2011.07.085

Reference yield:

: benzyl 4-pentadecen-1-yl ether

: 1337879-22-7
C₅₃H₁₀₂O₅Si₃

Guidance literature:: Multi-step reaction with 7 steps

1.1: AD-mix-α; methanesulfonamide; water / tert-butyl alcohol / 48 h / 0 °C

2.1: 2,6-dimethylpyridine / dichloromethane / 2 h / 20 °C / Cooling with ice; Inert atmosphere

3.1: palladium 10% on activated carbon; hydrogen / hexane / 3 h / 836.06 Torr

4.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere

4.2: 0.75 h / -78 - 20 °C / Inert atmosphere

5.1: tetrahydrofuran; diethyl ether / 1 h / -78 °C

5.2: 20 °C

6.1: 2,6-dimethylpyridine / dichloromethane / 2 h / 20 °C / Cooling with ice; Inert atmosphere

7.1: Grubbs catalyst first generation / dichloromethane / 4 h / Inert atmosphere; Reflux

With 2,6-dimethylpyridine; Grubbs catalyst first generation; oxalyl dichloride; methanesulfonamide; AD-mix-α; palladium 10% on activated carbon; water; hydrogen; dimethyl sulfoxide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; tert-butyl alcohol; 1.1: Sharpless dihydroxylation / 4.1: Swern oxidation / 4.2: Swern oxidation;
DOI:10.1016/j.tet.2011.07.085