N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine

Base Information

• Chemical Name: N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine
• CAS No.: 1202249-90-8
• Molecular Formula: C₁₆H₂₂N₂O₇
• Molecular Weight: 354.36
• Mol file: 1202249-90-8.mol

Synonyms:N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine

Chemical Property of N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine

There total 1 articles about N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

N-(benzyloxycarbonyl)glycine 2-(diphenylphosphanyl)-4-fluorophenyl ester (1202249-77-1) + β-L-fucopyranosyl azide (66347-26-0) → L-Fucose (2438-80-4,478518-52-4) + N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine (1202249-90-8) + C16H22N2O7

Guidance literature:

N-(benzyloxycarbonyl)glycine 2-(diphenylphosphanyl)-4-fluorophenyl ester; β-L-fucopyranosyl azide; In 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; N,N-dimethyl acetamide; at 20 - 40 ℃; Inert atmosphere;

With water; In 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; N,N-dimethyl acetamide; at 40 ℃; for 2h;

DOI:10.1002/ejoc.200900692

Reference yield: 100.0%

N-(N-benzyloxycarbonylglycyl)-β-L-fucopyranosylamine (1202249-90-8) + acetic anhydride (108-24-7) → N-(N-benzyloxycarbonylglycyl)-2,3,4-tri-O-acetyl-β-L-fucopyranosylamine (1202250-04-1)

Guidance literature:

With pyridine; dmap; at 20 ℃;

DOI:10.1002/ejoc.200900692

upstream raw materials:

N-(benzyloxycarbonyl)glycine 2-(diphenylphosphanyl)-4-fluorophenyl ester

β-L-fucopyranosyl azide

Downstream raw materials:

N-(N-benzyloxycarbonylglycyl)-2,3,4-tri-O-acetyl-β-L-fucopyranosylamine