2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Base Information

Chemical Name:2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
CAS No.:1117977-12-4
Molecular Formula:C₇₃H₇₆O₁₉
Molecular Weight:1257.4
Hs Code.:

Synonyms:2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Suppliers and Price of 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

There total 3 articles about 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1117977-09-9
C₃₉H₄₂O₁₄

: 74808-09-6
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 1117977-12-4
2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Guidance literature:: With iron(III) chloride; In dichloromethane; at -60 - 20 ℃; for 0.666667h; Inert atmosphere; Molecular sieve;
DOI:10.1039/c6ra21859h

Reference yield: 87.3%

: 74808-09-6
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 4064-06-6
1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

: 762287-64-9
S-4-methylphenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

: 1117977-12-4
2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Guidance literature:: 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate; S-4-methylphenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside; With iron(III) chloride; In dichloromethane; at -60 - 20 ℃; for 0.666667h; Inert atmosphere; Molecular sieve;

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose; With N-iodo-succinimide; In dichloromethane; at 0 - 20 ℃; for 0.25h; Inert atmosphere; Molecular sieve;
DOI:10.1039/c6ra21859h

Reference yield:

: 1117977-09-9
C₃₉H₄₂O₁₄

: 74808-09-6
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 1117977-12-4
2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-β-D-glucopyranosyl-(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

: C₇₃H₇₆O₁₉

Guidance literature:: With bis(benzonitrile)palladium(II) dichloride; silver trifluoromethanesulfonate; In dichloromethane; at -78 ℃; for 5h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/jo802468p