methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Base Information

Chemical Name:methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside
CAS No.:678159-03-0
Molecular Formula:C₂₂H₂₇NO₈
Molecular Weight:433.458
Hs Code.:

Synonyms:methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

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Chemical Property of methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

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Technology Process of methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

There total 5 articles about methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 678159-08-5
methyl 3-O-acetyl-4,6-O-benzylidene-2-deoxy-2-dimethylmaleimido-β-D-glucopyranose

: 678159-03-0
methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: With trimethylamine-borane; boron trifluoride diethyl etherate; In acetonitrile; at 0 - 20 ℃; for 1.5h;
DOI:10.1021/jo035583k

Reference yield:

: 898547-26-7
1-((2R,3R,4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3-yl)-3,4-dimethyl-pyrrole-2,5-dione

: 678159-03-0
methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 3.1 g / TsOH*H₂O / acetonitrile / 2 h / 20 °C

2: 85 percent / pyridine / 20 °C

3: 81 percent / BH₃*NMe₃; BF₃*Et₂O / acetonitrile / 1.5 h / 0 - 20 °C

With pyridine; trimethylamine-borane; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; In acetonitrile;
DOI:10.1021/jo035583k

Reference yield:

: 676487-75-5
methyl 3,4,6-tri-O-acetyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

: 678159-03-0
methyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: NaOMe / methanol / 0.5 h / 20 °C

2: 3.1 g / TsOH*H₂O / acetonitrile / 2 h / 20 °C

3: 85 percent / pyridine / 20 °C

4: 81 percent / BH₃*NMe₃; BF₃*Et₂O / acetonitrile / 1.5 h / 0 - 20 °C

With pyridine; trimethylamine-borane; boron trifluoride diethyl etherate; sodium methylate; toluene-4-sulfonic acid; In methanol; acetonitrile;
DOI:10.1021/jo035583k