2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol

Base Information

• Chemical Name: 2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol
• CAS No.: 660821-37-4
• Molecular Formula: C₁₆H₁₆N₂O₉
• Molecular Weight: 380.311
• Mol file: 660821-37-4.mol

Synonyms:2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol

Chemical Property of 2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol

There total 1 articles about 2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,6-anhydro-5-deoxy-3,4-O-isopropylidene-D-arabino-hex-5-enitol (124477-12-9) + 3,5-dinitrobenoyl chloride (99-33-2) → 2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol (660821-37-4)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 8h;

DOI:10.1002/chem.200305294

Reference yield: 92.0%

2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol (660821-37-4) → 2-bromo-2-deoxy-6-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-talopyranose

Guidance literature:

With N-bromoacetamide; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1002/chem.200305294

Reference yield: 69.0%

2,6-anhydro-5-deoxy-1-O-(3,5-dinitrobenzoyl)-3,4-O-isopropylidene-D-arabino-hex-5-enitol (660821-37-4) → 2-deoxy-6-O-(3,5-dinitrobenzoyl)-2-fluoro-3,4-O-isopropylidene-D-galactopyranose

Guidance literature:

With Selectfluor; In nitromethane; for 0.5h; Heating;

DOI:10.1002/chem.200305294

upstream raw materials:

2,6-anhydro-5-deoxy-3,4-O-isopropylidene-D-arabino-hex-5-enitol

3,5-dinitrobenoyl chloride