C₂₇H₄₁ClN₂O₄S

Base Information

Chemical Name:C₂₇H₄₁ClN₂O₄S
CAS No.:1354928-74-7
Molecular Formula:C₂₇H₄₁ClN₂O₄S
Molecular Weight:525.153
Hs Code.:

C<sub>27</sub>H<sub>41</sub>ClN<sub>2</sub>O<sub>4</sub>S

Synonyms:C₂₇H₄₁ClN₂O₄S

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Chemical Property of C₂₇H₄₁ClN₂O₄S

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Technology Process of C₂₇H₄₁ClN₂O₄S

There total 25 articles about C₂₇H₄₁ClN₂O₄S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1354928-48-5
(1'S,4'S,4a'S,5'R,6'R,8a'S)-5'-azido-4'-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6'-methyl-1-tosyloctahydro-2'H-spiro[aziridine-2,1'-naphthalen]-6'-ol

: 1354928-74-7
C₂₇H₄₁ClN₂O₄S

Guidance literature:: With sodium tetrahydroborate; nickel(II) chloride hexahydrate; In tetrahydrofuran; methanol; at 0 - 20 ℃; for 3.16667h;
DOI:10.1039/c1cc16468f

Reference yield:

: 440333-58-4
(2S,3R,6R)-2-{3-(benzyloxy)propyl}-6-(tert-butyldiphenylsilyloxy)-3,7-dimethyloct-7-ene-1,3-diol

: 1354928-74-7
C₂₇H₄₁ClN₂O₄S

Guidance literature:: Multi-step reaction with 21 steps

1.1: pyridine / 3 h / 20 °C

1.2: 24 h / 60 °C

2.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 48 h / 60 °C

3.1: 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine / dichloromethane / 0.08 h / 0 °C

4.1: diisobutylaluminium hydride / hexane; toluene / 0.17 h / -78 °C

5.1: pyridine / 0.5 h / 20 °C

6.1: iodonium(di-γ-collidine) perchlorate / dichloromethane / 4 h / 20 °C

7.1: triethyl borane; tri-n-butyl-tin hydride / tetrahydrofuran / 1 h / -78 °C

8.1: palladium 10% on activated carbon; hydrogen / methanol / 2.5 h / 20 °C

9.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

10.1: tetrahydrofuran / 0.17 h / 0 °C

11.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C

12.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.17 h / -78 °C

13.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

14.1: N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

14.2: 2 h / -78 - 20 °C

15.1: tetrabutyl ammonium fluoride / 2 h / 20 °C

16.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

17.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 °C

18.1: sodium azide; ammonium chloride / methanol; water / 10 h / Reflux

19.1: lithium hexamethyldisilazane / tetrahydrofuran / 3 h / -78 °C

20.1: copper(II) bis(trifluoromethanesulfonate) / acetonitrile / 3 h / 20 °C / Molecular sieve

21.1: sodium tetrahydroborate; nickel(II) chloride hexahydrate / tetrahydrofuran; methanol / 3.17 h / 0 - 20 °C

With pyridine; 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; sodium azide; nickel(II) chloride hexahydrate; 1,1,1,3,3,3-hexachloro-propan-2-one; triethyl borane; iodonium(di-γ-collidine) perchlorate; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; tri-n-butyl-tin hydride; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; sodium hydrogencarbonate; ammonium chloride; Dess-Martin periodane; acetic acid; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 16.1: intramolecular Diels-Alder reaction;
DOI:10.1039/c1cc16468f

Reference yield:

: C₂₅H₃₈ClIO₄

: 1354928-74-7
C₂₇H₄₁ClN₂O₄S

Guidance literature:: Multi-step reaction with 15 steps

1.1: triethyl borane; tri-n-butyl-tin hydride / tetrahydrofuran / 1 h / -78 °C

2.1: palladium 10% on activated carbon; hydrogen / methanol / 2.5 h / 20 °C

3.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

4.1: tetrahydrofuran / 0.17 h / 0 °C

5.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C

6.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.17 h / -78 °C

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

8.1: N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

8.2: 2 h / -78 - 20 °C

9.1: tetrabutyl ammonium fluoride / 2 h / 20 °C

10.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

11.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 °C

12.1: sodium azide; ammonium chloride / methanol; water / 10 h / Reflux

13.1: lithium hexamethyldisilazane / tetrahydrofuran / 3 h / -78 °C

14.1: copper(II) bis(trifluoromethanesulfonate) / acetonitrile / 3 h / 20 °C / Molecular sieve

15.1: sodium tetrahydroborate; nickel(II) chloride hexahydrate / tetrahydrofuran; methanol / 3.17 h / 0 - 20 °C

With 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; sodium azide; nickel(II) chloride hexahydrate; triethyl borane; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; tri-n-butyl-tin hydride; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; sodium hydrogencarbonate; ammonium chloride; Dess-Martin periodane; 3-chloro-benzenecarboperoxoic acid; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; 10.1: intramolecular Diels-Alder reaction;
DOI:10.1039/c1cc16468f