cis-Dichlorobis(dimethylphenylphosphine)palladium(II)

Base Information

• Chemical Name: cis-Dichlorobis(dimethylphenylphosphine)palladium(II)
• CAS No.: 15616-85-0
• Molecular Formula: C₁₆H₂₂Cl₂P₂Pd
• Molecular Weight: 453.624
• European Community (EC) Number: 620-783-8
• Mol file: 15616-85-0.mol

Synonyms:SCHEMBL3006122;cis-Dichlorobis(dimethylphenylphosphine)palladium(II);15616-85-0

Chemical Property of cis-Dichlorobis(dimethylphenylphosphine)palladium(II)

Chemical Property:

• Melting Point: 185-187 °C(lit.)
• PSA: 27.18000
• LogP: 4.95040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 451.96086
• Heavy Atom Count: 21
• Complexity: 75.4

Purity/Quality:

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CP(C)C1=CC=CC=C1.CP(C)C1=CC=CC=C1.Cl[Pd]Cl

Technology Process of cis-Dichlorobis(dimethylphenylphosphine)palladium(II)

There total 10 articles about cis-Dichlorobis(dimethylphenylphosphine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

cis-bis(phenylisocyanide)dichloropalladium (41762-42-9,40927-17-1) + Dimethyl(phenyl)phosphine (672-66-2) → cis-bis(dimethylphenylphosphine)dichloropalladium (29484-74-0,15616-85-0,29484-66-0)

Guidance literature:

In benzene; (Schlenk); addn. of phosphine to a soln. of palladium complex in benzene, stirring for 40 min; evapn., recrystn. (benzene);

DOI:10.1039/b512414j

Reference yield:

cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3) → trans-dichlorobis(dimethylphenylphosphine)palladium(II) (29484-66-0,15616-85-0,29484-74-0) + [PtPdCl4((C6H5)2PCCP(C6H5)2)2]*2CHCl3 (98087-77-5)

Guidance literature:

Multi-step reaction with 2 steps

1: xylene

2: CHCl₃ / benzene

With CHCl₃; In benzene;

Reference yield:

{(PPhMe2)ClPd(μ-Cl)2PtCl(PPhMe2)} (95387-54-5) → [Pt(dppe)Cl2] (14647-25-7,83095-83-4) + cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3) + trans-dichlorobis(dimethylphenylphosphine)palladium(II) (29484-66-0,15616-85-0,29484-74-0)

Guidance literature:

With bis-(diphenylphosphino)-ethane; In not given; detected by (31)P-NMR;;

upstream raw materials:

Dimethyl(phenyl)phosphine

potassium tetrachloropalladate(II)

cis-bis(phenylisocyanide)dichloropalladium

{(PPhMe2)ClPd(μ-Cl)2PtCl(PPhMe2)}

Downstream raw materials:

di(azido)bis(dimethylphenylphosphine)palladium(II)

bis(dimethylphenylphosphine)palladium(II) bromide

trans-dibromobis(dimethylphenylphosphine)palladium(II)

[(CH₃)2C₆H₅P]3PdCl⁽¹⁺⁾

Refernces

• 1、 Iwamoto, Takeaki,Sekiguchi, Yumiko,Yoshida, Naoki,Kabuto, Chizuko,Kira, Mitsuo. "Ligand dependence of π-complex character in disilene-palladium complexes". . p. 177 - 182. Retrieved 2007/10/03.
• 2、 Roberts, Nicholas K.,Skelton, Brian W.,White, Allan H.,Wild, Stanley, Bruce. "CATIONIC η5-CYCLOPENTADIENYLPALLADIUM(II) COMPLEXES. COMPOUNDS OF TYPE 5-C5H5)L2>PF6 CONTAINING . TERTIARY PHOSPHINES, ARSINES, AND STIBINES. CRYSTAL AND MOLECULAR STRUCTURE OF η5-CYCLOPENTADIENYLBIS(TRIPHENYLSTIBINE)PALLADIUM(II) HEXAFLUOROPHOSPHATE-DICHLOROMETHANE (1/1)". . p. 2093 - 2098. Retrieved 2007/10/02.