(4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

Base Information

• Chemical Name: (4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol
• CAS No.: 1111626-11-9
• Molecular Formula: C₂₆H₄₄O₄
• Molecular Weight: 420.633
• Mol file: 1111626-11-9.mol

Synonyms:(4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

Chemical Property of (4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

Chemical Property:

Purity/Quality:

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Technology Process of (4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

There total 1 articles about (4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(4R,5S)-5-((R)-1-(benzyloxy)tridecyl)-N-methoxy-N,2,2-trimethyl-1,3-dioxolane-4-carboxamide (1111626-10-8) → (4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol (1111626-11-9)

Guidance literature:

With sodium tetrahydroborate; In methanol; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetasy.2008.11.004

Reference yield: 84.0%

(4S,5S)-5-(((R)-1-(benzyloxy)tridecyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol (1111626-11-9) → (4S,5R)-5-((R)-1-(benzyloxy)tridecyl)-5-iodomethyl-2,2-dimethyl-1,3-dioxolane (1111626-07-3)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In toluene; for 1h; Inert atmosphere; Reflux;

DOI:10.1016/j.tetasy.2008.11.004

upstream raw materials:

(4R,5S)-5-((R)-1-(benzyloxy)tridecyl)-N-methoxy-N,2,2-trimethyl-1,3-dioxolane-4-carboxamide

Downstream raw materials:

(4S,5R)-5-((R)-1-(benzyloxy)tridecyl)-5-iodomethyl-2,2-dimethyl-1,3-dioxolane