Technology Process of C18H28OSi
There total 6 articles about C18H28OSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 2.131 g / O2 / Pd(OAc)2 / dimethylsulfoxide / 14 h / 23 °C / 760.05 Torr
2: tetrahydrofuran / 0.5 h / -78 °C
With
oxygen;
palladium diacetate;
In
tetrahydrofuran; dimethyl sulfoxide;
DOI:10.1021/ol990805f
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 93 percent / PDC; 4 Angstroem molecular sieves / CH2Cl2 / 26 h / 23 °C
2: lithium hexamethyldisilazane; Et3N / tetrahydrofuran / -78 °C
3: 2.131 g / O2 / Pd(OAc)2 / dimethylsulfoxide / 14 h / 23 °C / 760.05 Torr
4: tetrahydrofuran / 0.5 h / -78 °C
With
dipyridinium dichromate; 4 A molecular sieve; oxygen; triethylamine; lithium hexamethyldisilazane;
palladium diacetate;
In
tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol990805f
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 99 percent / LiAl(t-BuO)3H / tetrahydrofuran / 16 h / -60 °C
2: Amano Lipase PS / diisopropyl ether / 60 h / 23 °C
3: 93 percent / PDC; 4 Angstroem molecular sieves / CH2Cl2 / 26 h / 23 °C
4: lithium hexamethyldisilazane; Et3N / tetrahydrofuran / -78 °C
5: 2.131 g / O2 / Pd(OAc)2 / dimethylsulfoxide / 14 h / 23 °C / 760.05 Torr
6: tetrahydrofuran / 0.5 h / -78 °C
With
dipyridinium dichromate; Amano Lipase PS; 4 A molecular sieve; oxygen; lithium tri-t-butoxyaluminum hydride; triethylamine; lithium hexamethyldisilazane;
palladium diacetate;
In
tetrahydrofuran; dichloromethane; di-isopropyl ether; dimethyl sulfoxide;
DOI:10.1021/ol990805f
