N-PHENYL-9-ANTHRAMINE

Base Information

• Chemical Name: N-PHENYL-9-ANTHRAMINE
• CAS No.: 15424-38-1
• Molecular Formula: C20H15N
• Molecular Weight: 269.346
• Hs Code.: 2921499090
• Mol file: 15424-38-1.mol

Synonyms:N-(9-Anthracenyl)aniline;9-Anthracenylphenylamine;9-Anthramine,N-phenyl- (6CI,7CI,8CI);(9-Anthryl)phenylamine;9-anthracenamine, N-phenyl-;N-Phenylanthracen-9-amine;

Chemical Property of N-PHENYL-9-ANTHRAMINE

Chemical Property:

• Melting Point: 207 °C
• Refractive Index: 1.752
• Boiling Point: 434.355 °C at 760 mmHg
• PKA: 0.78±0.30(Predicted)
• Flash Point: 233.262 °C
• PSA: 12.03000
• Density: 1.204 g/cm³
• LogP: 5.80960
• Solubility.: almost transparency in Acetone

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-Phenyl-9-anthramine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-PHENYL-9-ANTHRAMINE

There total 6 articles about N-PHENYL-9-ANTHRAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

9-Bromoanthracene (1564-64-3) + aniline (62-53-3) → 9-(N-phenylamino)anthracene (15424-38-1)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trineopentyl phosphine; sodium t-butanolate; In toluene; at 80 ℃; for 3h; Inert atmosphere; Glovebox;

DOI:10.1021/jo400435z

Reference yield: 85.0%

9-chloroanthracene (716-53-0) + aniline (62-53-3) → 9-(N-phenylamino)anthracene (15424-38-1)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 2h; Reflux;

Reference yield: 83.9%

→ 9-(N-phenylamino)anthracene (15424-38-1)

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In cyclohexane; toluene; for 2h; Inert atmosphere; Reflux;

upstream raw materials:

9-Bromoanthracene

aniline

Acetanilid

bromobenzene

Downstream raw materials:

9H,9'H-[9,9']bianthryl-10,10'-dione-bis-phenylimine

9H,9'H-[9,9']bianthryl-10,10'-dione-bis-(4-nitro-phenylimine)

9,9-bis-benzoyloxy-10-phenylimino-9,10-dihydro-anthracene

N-(anthracen-9-yl)-6-butyl-N-phenyl-6H-indolo[2,3-b]quinoxalin-9-amine

Refernces

• 1、 -. "Aromatic amine derivative, and preparation method and application thereof". Paragraph 0051; 0052; 0053. . Retrieved 2017/08/28.
• 2、 -. "A and quinoline derivatives thereof in organic electroluminescent the application in the field of". Paragraph 0053; 0054; 0150; 0151; 0152. . Retrieved 2016/10/07.