Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan

Base Information

• Chemical Name: Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan
• CAS No.: 101069-15-2
• Molecular Formula: C₂₀H₄₂FNSi₄
• Molecular Weight: 427.901
• Mol file: 101069-15-2.mol

Synonyms:Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan

Chemical Property of Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan

There total 2 articles about Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,4,6-trimethylaniline (88-05-1) + Difluor-methylsilyl-tris(trimethylsilyl)methan (101069-14-1) → Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan (101069-15-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; for 2h; Heating;

DOI:10.1016/0022-328X(85)80180-7

Reference yield:

tris(trimethylsilyl)methyllithium (28830-22-0) → Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan (101069-15-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 69 percent / tetrahydrofuran / -40 °C

2: 1.) 15percent n-C₄H₉Li / 1.) hexane, 2.) 8 h, reflux

With n-butyllithium; In tetrahydrofuran;

Reference yield: 38.0%

Fluor-methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methylsilan (101069-15-2) → Methyl-(2,4,6-trimethylphenyl-trimethylsilyl)amino-bis(trimethylsilyl)methyl-silanol + <1-Methyl-1-(trimethylsilyl)methyl-1-(trimethylsilyl-2,4,6-trimethylphenyl)amino>-3,3,3-trimethyl-1,3-disiloxan

Guidance literature:

With potassium hydroxide; at 160 ℃; for 2h;

upstream raw materials:

2,4,6-trimethylaniline

Difluor-methylsilyl-tris(trimethylsilyl)methan

tris(trimethylsilyl)methyllithium