TRIS(ACETONITRILE)TRICARBONYLMOLYBDENUM

Base Information

• Chemical Name: TRIS(ACETONITRILE)TRICARBONYLMOLYBDENUM
• CAS No.: 15038-48-9
• Molecular Formula: C₉H₉MoN₃O₃
• Molecular Weight: 303.129
• Hs Code.: 29310099
• Mol file: 15038-48-9.mol

Synonyms:Triacetonitriletricarbonylmolybdenum; Tricarbonyltris(acetonitrile)molybdenum;Tris(acetonitrile)molybdenum tricarbonyl;Tris(acetonitrile)tricarbonylmolybdenum;Tris(acetonitrile)tris(carbonyl)molybdenum

Chemical Property of TRIS(ACETONITRILE)TRICARBONYLMOLYBDENUM

Chemical Property:

• Melting Point: 90 °C (dec.)(lit.)
• PSA: 71.37000
• LogP: 0.96564

Purity/Quality:

98%Min ^*data from raw suppliers

TRIS(ACETONITRILE)MOLYBDENUM TRICARBONYL 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 36/37/39-26-22

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(ACETONITRILE)TRICARBONYLMOLYBDENUM

There total 16 articles about TRIS(ACETONITRILE)TRICARBONYLMOLYBDENUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

acetonitrile (75-05-8,26809-02-9) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → tris(acetonitrile)tricarbonylmolybdenum(0) (15038-48-9,17731-95-2)

Guidance literature:

In acetonitrile; dry, inert atm., under N2, 48 h, reflux; concn., extn. (pentane, diethylether), evapn. (vacuum);

DOI:10.1016/0022-328X(86)80197-8

Reference yield: 85.0%

Mo(CO)3(1,3,5-trimethyl-1,3,5-triazacyclohexane) (205106-36-1) + acetonitrile (75-05-8,26809-02-9) → fac-[Mo(CO)3(acetonitrile)3] (15038-48-9,17731-95-2)

Guidance literature:

In acetonitrile; N2-atmosphere; pptn. on PhMe addn., collection (filtration), washing (hexanes), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(98)00642-1

Reference yield: 36.0%

[Mo(CO)3(μ-η(6):η(1)-C7H7)Ru(CO)2(η-C5Me5)] + acetonitrile (75-05-8,26809-02-9) → tris(acetonitrile)tricarbonylmolybdenum(0) (15038-48-9,17731-95-2) + [Ru(η(1)-C7H7)(CO)2(η-C5Me5)] (180070-44-4)

Guidance literature:

In acetonitrile; N2-atmosphere; stirring for 15 min; evapn., dissoln. in PhMe, chromy. (Al2O3, PhMe), evapn., dissoln. in hexane, filtration, cooling to -78°C (pptn.); elem. anal.;

DOI:10.1016/S0022-328X(96)06235-3

upstream raw materials:

Mo(CO)3(1,3,5-trimethyl-1,3,5-triazacyclohexane)

acetonitrile

molybdenum hexacarbonyl

[Mo(carbonyl)3(1,3,5-tris(thiocyanatomethyl)mesitylene)]

Downstream raw materials:

fac-Mo(CO)3P[N(C₆H₅)PF₂]3

dicarbonylbis(η4-4,5-diethyl-2,5-dihydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborole)molybdenum

tetracarbonyl(η4-4,5-diethyl-2,5-dihydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborole)molybdenum

[Mo(η(3)-C3H4(Me-1))(CO)2(S2PPh2)(NCMe)]