TRIS(ETHYLENEDIAMINE)RHODIUM(III) TRICHLORIDE

Base Information

• Chemical Name: TRIS(ETHYLENEDIAMINE)RHODIUM(III) TRICHLORIDE
• CAS No.: 15004-86-1
• Molecular Formula: C₆H₂₄N₆Rh*3Cl*3H₂O
• Molecular Weight: 443.607
• Mol file: 15004-86-1.mol

Synonyms:Rhodium(3+),tris(1,2-ethanediamine-N,N')-, trichloride, trihydrate, (OC-6-11)-;Rhodium(3+), tris(ethylenediamine)-, trichloride, trihydrate (8CI);Tris(ethylenediamine)rhodium(3+) trichloride trihydrate

Chemical Property of TRIS(ETHYLENEDIAMINE)RHODIUM(III) TRICHLORIDE

Chemical Property:

• Melting Point: >300 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 183.81000
• Density: g/cm³
• LogP: 2.78880

Purity/Quality:

99% ^*data from raw suppliers

Tris(ethylenediamine)rhodium(III) chloride trihydrate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Used as precursor for supported RH catalyst.

Technology Process of TRIS(ETHYLENEDIAMINE)RHODIUM(III) TRICHLORIDE

There total 9 articles about TRIS(ETHYLENEDIAMINE)RHODIUM(III) TRICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Rh(NH2CH2CH2NH2)2(OSO2CF3)2(1+)*CF3SO3(1-)=[Rh(NH2CH2CH2NH2)2(OSO2CF3)2](CF3SO3) (90065-93-3) → [Rh(ethylenediamine)3]Cl3 * 3H2O (15004-86-1)

Guidance literature:

With ethylenediamine; In ethylenediamine; heated (steam bath, 10 min); addn. of ether and EtOH to the cooled soln. (stirring), ppt. collected,boiled (CHCl3), collected, air-dried, recrystd. (aq. HCl); elem. anal.;

Reference yield:

rhodium(III) chloride trihydrate → [Rh(ethylenediamine)3]Cl3 * 3H2O (15004-86-1)

Guidance literature:

With ethylenediamine; In water; boiling;

Reference yield:

[Rh(ethylenediamine)3]Cl3 * 3H2O (15004-86-1) → (-)-{Rh(en)3}Cl3*2H2O (15004-86-1) + (+)-{Rh(en)3}Cl3*3H2O (15004-86-1)

Guidance literature:

With Li tartrate; In water;

upstream raw materials:

1,2-ethanediamine monohydrate

Rh(NH₂CH₂CH₂NH₂)2(OSO₂CF₃)2⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(NH₂CH₂CH₂NH₂)2(OSO₂CF₃)2](CF₃SO₃)

rhodium(III)chloride

Refernces