Technology Process of [potassium(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane)][tetrakis(2,6-dimethylphenyl isocyano)cobaltate(-I)]
There total 1 articles about [potassium(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane)][tetrakis(2,6-dimethylphenyl isocyano)cobaltate(-I)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
under N2; redn. of soln. Co-complex/THF by dropwise addn. 2.1 molar equiv K(C10H8)/THF at -78°C, addn. (cannula) of the cryptand/THF, mixt. stirred (15 min, -78°C), slowly warmed to room temp.; Et2O carefully layered on top of soln,., mixt. left overnight (black cryst.), mother liquor removed via cannula, additional Et2O added, mixt. kept at -78°C overnight, the two crops of cryst. washed (Et2O, 3 times), dried (vac., overnight);
DOI:10.1021/ja00098a017
- Guidance literature:
-
With
O2;
In
not given;
oxidation of soln. of Co-complex; not isolated, detected by IR-spect.;
DOI:10.1021/ja00098a017
