bis(cyclopentadienyl)benzylchlorotungsten

Base Information

Chemical Name:bis(cyclopentadienyl)benzylchlorotungsten
CAS No.:100113-66-4
Molecular Formula:C₁₇H₁₇ClW
Molecular Weight:440.625
Hs Code.:

Synonyms:bis(cyclopentadienyl)benzylchlorotungsten

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Chemical Property of bis(cyclopentadienyl)benzylchlorotungsten

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Technology Process of bis(cyclopentadienyl)benzylchlorotungsten

There total 2 articles about bis(cyclopentadienyl)benzylchlorotungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 100113-65-3
bis(cyclopentadienyl)benzylchlorotungsten hexafluorophosphate

: 100113-66-4
bis(cyclopentadienyl)benzylchlorotungsten

Guidance literature:: With potassium hydroxide; In water; acetone; an acetone soln. of (Cp2W(CH2Ph)Cl)PF6 was vigorously stirred with a satd. soln. of aq. KOH at room temp. under inert atmosphere for 0.5 h; org. layer was decanted off, solvent removed under reduced pressure, residue was extd. with CH2Cl2, ext. filtered, concd. under reduced pressure; identified by (1)H NMR spectral data;
DOI:10.1021/om00135a021

Reference yield: 56.0%

: 53770-69-7
bis(cyclopentadienyl)benzyl(ethylene)tungsten hexafluorophosphate

: 75-57-0
tetramethlyammonium chloride

: 100113-66-4
bis(cyclopentadienyl)benzylchlorotungsten

Guidance literature:: In N,N-dimethyl-formamide; a slurry of Cp2W(CH2Ph)(CH2=CH2)PF6 and NMe4Cl in DMF was stirred at 72°C under inert atmosphere for 15 h; filtered, Et2O and water added, soln. was vigorously shaken, ether layer collected, washed with water, filtered, evapd. in vacuo to give spect.pure ((1)H NMR) product, anal. pure material was obtained via slow concn. of a satd. ether soln.; elem. anal.;
DOI:10.1021/om00135a021

Reference yield: 71.0%

: 100113-66-4
bis(cyclopentadienyl)benzylchlorotungsten

: 437-17-2
tritylium hexafluorophosphate

: W(C₅H₅)2(CHC₆H₅)Cl⁽¹⁺⁾

: 100113-65-3
bis(cyclopentadienyl)benzylchlorotungsten hexafluorophosphate

Guidance literature:: In dichloromethane; a CH2Cl2 soln. of Ph3CPF6 was added under inert atmosphere to a stirredCH2Cl2 soln. of Cp2W(CH2Ph)Cl; no evidence for benzylidene complex formation was observed; ppt. was collected by decantation, washed with CH2Cl2, dried under vac.; identified spect. (IR and ESR);
DOI:10.1021/om00135a021