Bicyclo[10.3.0]pentadec-1(12)-en-13-one

Base Information

• Chemical Name: Bicyclo[10.3.0]pentadec-1(12)-en-13-one
• CAS No.: 15210-25-0
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.355
• European Community (EC) Number: 604-824-7
• DSSTox Substance ID: DTXSID501153067
• Nikkaji Number: J2.891.290K
• Mol file: 15210-25-0.mol

Synonyms:SCHEMBL8070883;XJLVRZOPNZLSSM-UHFFFAOYSA-N;DTXSID501153067;bicyclo[10.3.0]pentadec-1(12)-en-13-one;bicyclo[10.3.0]pentadec-12(1)-en-13 one;Bicyclo[10.3.0]pentadecane-1(12)-ene-13-one;2,3,4,5,6,7,8,9,10,11,12,13-Dodecahydro-1H-cyclopentacyclododecen-1-one;15210-25-0

Chemical Property of Bicyclo[10.3.0]pentadec-1(12)-en-13-one

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 220.182715385
• Heavy Atom Count: 16
• Complexity: 275

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCCCC2=C(CCCC1)CCC2=O

Technology Process of Bicyclo[10.3.0]pentadec-1(12)-en-13-one

There total 26 articles about Bicyclo[10.3.0]pentadec-1(12)-en-13-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(6E,10E)-2,3,4,5,8,9,12,13-Octahydro-cyclopentacyclododecen-1-one → bicyclo[10.3.0]pentadec-1(12)-en-13-one (15210-25-0)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethyl acetate;

DOI:10.1016/S0040-4039(01)90055-3

Reference yield: 90.0%

bicyclo[10.3.0]pentadec-1-en-3-one → bicyclo[10.3.0]pentadec-1(12)-en-13-one (15210-25-0)

Guidance literature:

With rhodium(III) chloride; In ethanol; at 14 ℃; Heating;

DOI:10.1007/BF02495926

Reference yield: 90.0%

1-(3.3-Dichlorpropenyl)cyclododecanol (67220-92-2) → bicyclo[10.3.0]pentadec-1(12)-en-13-one (15210-25-0)

Guidance literature:

With trifluoroacetic acid; for 1.5h; Ambient temperature;

DOI:10.1246/bcsj.53.1010

upstream raw materials:

3-oxo-2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-1H-cyclopentacyclododecene-1-carboxylic acid ethyl ester

2-Cyclododecylidene-succinic acid 1-ethyl ester

1-oxaspiro[4.11]hexadecan-2-one

1-ethynylcyclododecan-1-ol

Downstream raw materials:

methyl p-toluene sulfinate

methyl p-toluene sulfonate

cyclopentadec-4-yn-1-one

cyclopentadecanone